Phosphonium cation-containing polymers: From ionic liquids to polyelectrolytes

Chainika Jangu, Timothy Edward Long

Research output: Contribution to journalArticle

55 Citations (Scopus)

Abstract

Phosphonium cation-based ionic liquids (ILs) are a readily available family of ILs that often offer superior properties compared to ammonium cation-based ILs. Recently investigated applications include extraction solvents, electrolytes in batteries and super-capacitors, and corrosion protection. At the same time, the range of cation-anion combinations available commercially has also increased in recent years. Polymerized ionic liquids and polyelectrolytes play major roles in a broad range of biological applications including antimicrobials, non-viral gene delivery, synthetic enzymes, metal chelation, and drug delivery. Ammonium- and phosphonium-containing macromolecules will be reviewed with a focus on structure-property relationships of these polyelectrolytes and ionic liquids. Phosphonium-containing macromolecules often display enhanced performance compared to ammonium analogs.

Original languageEnglish
Pages (from-to)3298-3304
Number of pages7
JournalPolymer (United Kingdom)
Volume55
Issue number16
DOIs
Publication statusPublished - 2014 Aug 5
Externally publishedYes

Keywords

  • Ionic liquids
  • Macromolecules
  • Polyelectrolytes

ASJC Scopus subject areas

  • Organic Chemistry
  • Polymers and Plastics

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