PHOSPHORUS DISTRIBUTION BETWEEN Na2O-SiO2-FeO SLAG AND CARBON-SATURATED IRON AT HOT METAL TEMPERATURES.

Kimihisa Ito, Nobuo Sano

Research output: Contribution to journalArticle

6 Citations (Scopus)

Abstract

The equilibrium distribution of phosphorus between Na//2O-SiO//2-FeO melts and carbon-saturated iron in the soda-ash treatment process was measured at 1,300 degree C using a solid iron strip. The logarithm of the phosphate capacity of the system increases from 19. 5 to 24. 8 with increasing the basicity index (X(Na//2O) plus X(Na//2CO//3 /X(SiO//2) ) plus X(PO(2. 5) ) plus X(FeO(1. 5)) from 0. 7 to 1. 2, where X//i represent the molar fractions of bases. Iron oxide decreases the phosphate capacity of the slags. The phosphate capacity of the slag used in the soda-ash treatment is found to be very high, having the logarithm of phosphate capacity of about 31. The partial oxygen pressure at the slag-metal interface is estimated to be at 10** minus **1**5 to 10** minus **1**6, which is much lower than the process using CaO-base slag.

Original languageEnglish
Pages (from-to)1838-1840
Number of pages3
JournalTetsu-To-Hagane/Journal of the Iron and Steel Institute of Japan
Volume69
Issue number15
DOIs
Publication statusPublished - 1983 Jan 1
Externally publishedYes

ASJC Scopus subject areas

  • Condensed Matter Physics
  • Physical and Theoretical Chemistry
  • Metals and Alloys
  • Materials Chemistry

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