PHOTO-REDUCTION OF POLY(VIOLOGEN) AND HYDROGEN EVOLUTION FROM WATER.

Guo Xiang Wan, Naoki Shimidzu, Hiroyuki Nishide, Eishun Tsuchida

Research output: Contribution to journalArticle

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Abstract

Poly(xylylviologen) and poly(decaneviologen) were photochemically reduced in the presence of ethylenediamine tetraacetic acid as a reductant and trisbipyridine Ru as a sensitizer. The cation radical of the polyviologen was efficiently accumulated although the rate constant of electron transfer from the Ru complex to the polyviologen was smaller than that of methylviologen. Hydrogen was evolved from water by further addition of colloidal platinum under visible light irradiation.

Original languageEnglish
Pages (from-to)121-124
Number of pages4
JournalWaseda Daigaku Rikogaku Kenkyusho Hokoku/Bulletin of Science and Engineering Research Laboratory,
Issue number105
Publication statusPublished - 1983
Externally publishedYes

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Platinum
Rate constants
Positive ions
Irradiation
Hydrogen
Acids
Electrons
Water

ASJC Scopus subject areas

  • Engineering(all)

Cite this

PHOTO-REDUCTION OF POLY(VIOLOGEN) AND HYDROGEN EVOLUTION FROM WATER. / Wan, Guo Xiang; Shimidzu, Naoki; Nishide, Hiroyuki; Tsuchida, Eishun.

In: Waseda Daigaku Rikogaku Kenkyusho Hokoku/Bulletin of Science and Engineering Research Laboratory, No. 105, 1983, p. 121-124.

Research output: Contribution to journalArticle

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