Photocatalytic reduction of CO 2 with H 2O on Ti-containing porous silica thin film photocatalysts

Keita Ikeue, Shinjiro Nozaki, Makoto Ogawa, Masakazu Anpo

Research output: Contribution to journalArticle

75 Citations (Scopus)

Abstract

Two different Ti-containing porous silica thin films having a hexagonal and cubic pore structure were synthesized and used as photocatalysts for the reduction of CO 2 with H 2O at 323 K. UV irradiation of the Ti-containing porous silica thin films in the presence of CO 2 and H 2O led to the formation of CH 4 and CH 3OH with a high quantum yield of 0.28%. These porous silica thin film photocatalysts having a hexagonal pore structure exhibited higher reactivity than the Ti-MCM-41 powder photocatalysts with the same pore structure.

Original languageEnglish
Pages (from-to)111-114
Number of pages4
JournalCatalysis Letters
Volume80
Issue number3-4
DOIs
Publication statusPublished - 2002 Jun

Fingerprint

Carbon Monoxide
Photocatalysts
Pore structure
Silicon Dioxide
Silica
silicon dioxide
porosity
Thin films
thin films
methylidyne
Multicarrier modulation
Quantum yield
Powders
reactivity
Irradiation
irradiation

Keywords

  • Formation of CH OH
  • Mesoporous thin film
  • Photocatalyst
  • Quantum yield
  • Reduction of CO

ASJC Scopus subject areas

  • Physical and Theoretical Chemistry
  • Catalysis

Cite this

Photocatalytic reduction of CO 2 with H 2O on Ti-containing porous silica thin film photocatalysts. / Ikeue, Keita; Nozaki, Shinjiro; Ogawa, Makoto; Anpo, Masakazu.

In: Catalysis Letters, Vol. 80, No. 3-4, 06.2002, p. 111-114.

Research output: Contribution to journalArticle

Ikeue, Keita ; Nozaki, Shinjiro ; Ogawa, Makoto ; Anpo, Masakazu. / Photocatalytic reduction of CO 2 with H 2O on Ti-containing porous silica thin film photocatalysts. In: Catalysis Letters. 2002 ; Vol. 80, No. 3-4. pp. 111-114.
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