Photochromogenic nanosheet crystallites of tungstate with a 2D bronze structure

Katsutoshi Fukuda, Kosho Akatsuka, Yasuo Ebina, Minoru Osada, Wataru Sugimoto, Mutsumi Kimura, Takayoshi Sasaki

Research output: Contribution to journalArticle

24 Citations (Scopus)

Abstract

Layered rubidium tungstate, Rb 4W 11O 35, with a two-dimensional (2D) bronze-type tunnel structure was successfully delaminated into colloidal nanosheets via a soft-chemical process involving acid exchange and subsequent intercalation of tetrabutylammonium ions. Characterizations by transmission electron microscopy and atomic force microscopy confirmed the formation of unilamellar 2D nanosheet crystallites with a unique thickness of ∼3 nm and an average lateral size of 400 nm. The obtained nanosheets exhibited reversible color change upon UV-light excitation via an optical band gap of 3.5 eV. The ultimate 2D aspect ratio favorable for an adsorption of charge-compensating cations to trapped electrons working as a color center is presumably responsible for highly efficient photochromic behavior. Its coloration mainly consists of a broad band at a wavelength of 1800 nm and longer, which is much different from that of the common tungstate nanomaterials. Thus, the chromogenic nanosheet obtained in this study features the intense UV absorption and optically switchable visible-to-IR absorption, which may be useful for window applications such as cutoff filters and heat-absorbing films.

Original languageEnglish
Pages (from-to)1540-1543
Number of pages4
JournalInorganic Chemistry
Volume51
Issue number3
DOIs
Publication statusPublished - 2012 Feb 6
Externally publishedYes

ASJC Scopus subject areas

  • Inorganic Chemistry
  • Physical and Theoretical Chemistry

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    Fukuda, K., Akatsuka, K., Ebina, Y., Osada, M., Sugimoto, W., Kimura, M., & Sasaki, T. (2012). Photochromogenic nanosheet crystallites of tungstate with a 2D bronze structure. Inorganic Chemistry, 51(3), 1540-1543. https://doi.org/10.1021/ic201834y