Photocontrolled formation of hydroxyl-bearing monolayers and multilayers

Rochael J. Collins, In Tae Bae, Daniel Alberto Scherson, Chaim N. Sukenik

Research output: Contribution to journalArticle

30 Citations (Scopus)

Abstract

Siloxane-anchored, nitrate-bearing, monolayer films have been fabricated and have been used as the precursors for the photochemical creation of uniformly hydroxylated monolayer surfaces. The surface hydroxyl groups have been shown to be reactive toward phosphorylation and, more importantly, they can serve as the base layer for addition of a subsequent siloxane-anchored monolayer. This approach provides an important new tool for monolayer transformation and allows for photocontrol of organic multilayer construction.

Original languageEnglish
Pages (from-to)5509-5511
Number of pages3
JournalLangmuir
Volume12
Issue number23
Publication statusPublished - 1996 Nov 13
Externally publishedYes

Fingerprint

Bearings (structural)
siloxanes
Hydroxyl Radical
Monolayers
Multilayers
Siloxanes
phosphorylation
nitrates
Phosphorylation
Nitrates

ASJC Scopus subject areas

  • Materials Science(all)
  • Condensed Matter Physics
  • Surfaces and Interfaces
  • Spectroscopy
  • Electrochemistry

Cite this

Collins, R. J., Bae, I. T., Scherson, D. A., & Sukenik, C. N. (1996). Photocontrolled formation of hydroxyl-bearing monolayers and multilayers. Langmuir, 12(23), 5509-5511.

Photocontrolled formation of hydroxyl-bearing monolayers and multilayers. / Collins, Rochael J.; Bae, In Tae; Scherson, Daniel Alberto; Sukenik, Chaim N.

In: Langmuir, Vol. 12, No. 23, 13.11.1996, p. 5509-5511.

Research output: Contribution to journalArticle

Collins, RJ, Bae, IT, Scherson, DA & Sukenik, CN 1996, 'Photocontrolled formation of hydroxyl-bearing monolayers and multilayers', Langmuir, vol. 12, no. 23, pp. 5509-5511.
Collins RJ, Bae IT, Scherson DA, Sukenik CN. Photocontrolled formation of hydroxyl-bearing monolayers and multilayers. Langmuir. 1996 Nov 13;12(23):5509-5511.
Collins, Rochael J. ; Bae, In Tae ; Scherson, Daniel Alberto ; Sukenik, Chaim N. / Photocontrolled formation of hydroxyl-bearing monolayers and multilayers. In: Langmuir. 1996 ; Vol. 12, No. 23. pp. 5509-5511.
@article{88495e9f217e4b7390c42a23257b3592,
title = "Photocontrolled formation of hydroxyl-bearing monolayers and multilayers",
abstract = "Siloxane-anchored, nitrate-bearing, monolayer films have been fabricated and have been used as the precursors for the photochemical creation of uniformly hydroxylated monolayer surfaces. The surface hydroxyl groups have been shown to be reactive toward phosphorylation and, more importantly, they can serve as the base layer for addition of a subsequent siloxane-anchored monolayer. This approach provides an important new tool for monolayer transformation and allows for photocontrol of organic multilayer construction.",
author = "Collins, {Rochael J.} and Bae, {In Tae} and Scherson, {Daniel Alberto} and Sukenik, {Chaim N.}",
year = "1996",
month = "11",
day = "13",
language = "English",
volume = "12",
pages = "5509--5511",
journal = "Langmuir",
issn = "0743-7463",
publisher = "American Chemical Society",
number = "23",

}

TY - JOUR

T1 - Photocontrolled formation of hydroxyl-bearing monolayers and multilayers

AU - Collins, Rochael J.

AU - Bae, In Tae

AU - Scherson, Daniel Alberto

AU - Sukenik, Chaim N.

PY - 1996/11/13

Y1 - 1996/11/13

N2 - Siloxane-anchored, nitrate-bearing, monolayer films have been fabricated and have been used as the precursors for the photochemical creation of uniformly hydroxylated monolayer surfaces. The surface hydroxyl groups have been shown to be reactive toward phosphorylation and, more importantly, they can serve as the base layer for addition of a subsequent siloxane-anchored monolayer. This approach provides an important new tool for monolayer transformation and allows for photocontrol of organic multilayer construction.

AB - Siloxane-anchored, nitrate-bearing, monolayer films have been fabricated and have been used as the precursors for the photochemical creation of uniformly hydroxylated monolayer surfaces. The surface hydroxyl groups have been shown to be reactive toward phosphorylation and, more importantly, they can serve as the base layer for addition of a subsequent siloxane-anchored monolayer. This approach provides an important new tool for monolayer transformation and allows for photocontrol of organic multilayer construction.

UR - http://www.scopus.com/inward/record.url?scp=0001767677&partnerID=8YFLogxK

UR - http://www.scopus.com/inward/citedby.url?scp=0001767677&partnerID=8YFLogxK

M3 - Article

AN - SCOPUS:0001767677

VL - 12

SP - 5509

EP - 5511

JO - Langmuir

JF - Langmuir

SN - 0743-7463

IS - 23

ER -