Photoluminescent Cu(i): Vs. Ag(i) complexes: Slowing down emission in Cu(i) complexes by pentacoordinate low-lying excited states

José M. Carbonell-Vilar, Elisa Fresta, Donatella Armentano, Rubén D. Costa, Marta Viciano-Chumillas, Joan Cano

Research output: Contribution to journalArticle

6 Citations (Scopus)

Abstract

This work describes the synthesis, and structural, spectroscopic, and theoretical studies of a mononuclear silver(i) complex with the formula [Ag(Xantphos)(4,4′-(MeO)2-2,2′-bipy)]BF4·DCM (1·BF4) [Xantphos: 4,5-bis(diphenylphosphino)-9,9′-dimethylxanthene]. We provide meaningful insights into the enhancement of the photoluminescence features of this silver(i) complex compared to its copper(i) analogue.

Original languageEnglish
Pages (from-to)9765-9775
Number of pages11
JournalDalton Transactions
Volume48
Issue number26
DOIs
Publication statusPublished - 2019
Externally publishedYes

ASJC Scopus subject areas

  • Inorganic Chemistry

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