TY - JOUR
T1 - Photoluminescent Cu(i)
T2 - Vs. Ag(i) complexes: Slowing down emission in Cu(i) complexes by pentacoordinate low-lying excited states
AU - Carbonell-Vilar, José M.
AU - Fresta, Elisa
AU - Armentano, Donatella
AU - Costa, Rubén D.
AU - Viciano-Chumillas, Marta
AU - Cano, Joan
PY - 2019
Y1 - 2019
N2 - This work describes the synthesis, and structural, spectroscopic, and theoretical studies of a mononuclear silver(i) complex with the formula [Ag(Xantphos)(4,4′-(MeO)2-2,2′-bipy)]BF4·DCM (1·BF4) [Xantphos: 4,5-bis(diphenylphosphino)-9,9′-dimethylxanthene]. We provide meaningful insights into the enhancement of the photoluminescence features of this silver(i) complex compared to its copper(i) analogue.
AB - This work describes the synthesis, and structural, spectroscopic, and theoretical studies of a mononuclear silver(i) complex with the formula [Ag(Xantphos)(4,4′-(MeO)2-2,2′-bipy)]BF4·DCM (1·BF4) [Xantphos: 4,5-bis(diphenylphosphino)-9,9′-dimethylxanthene]. We provide meaningful insights into the enhancement of the photoluminescence features of this silver(i) complex compared to its copper(i) analogue.
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U2 - 10.1039/c9dt00772e
DO - 10.1039/c9dt00772e
M3 - Article
C2 - 31011739
AN - SCOPUS:85068146748
SN - 1477-9226
VL - 48
SP - 9765
EP - 9775
JO - Dalton Transactions
JF - Dalton Transactions
IS - 26
ER -