Picosecond pulse radiolysis on geminate ion recombination and formation of solute excited state in liquid cyclohexane

Y. Yoshida, S. Tagawa, Masakazu Washio, H. Kobayashi, Y. Tabata

Research output: Contribution to journalArticle

1 Citation (Scopus)

Abstract

The geminate ion recombination and the formation process of solute excited states in solutions of biphenyl were studied in cyclohexane by means of picosecond pulse radiolysis with absorption and emission spectroscopies. The time-dependent behavior of the biphenyl anion was analyzed with the diffusion theory in the solute-solvent system. By applying this analysis to the time-dependent fluorescence from excited states of biphenyl, yields of the excited states through various formation processes were deduced. Also, yield of excited states of cyclohexane in the absence of solutes was estimated.

Original languageEnglish
Pages (from-to)493-496
Number of pages4
JournalInternational Journal of Radiation Applications and Instrumentation. Part
Volume34
Issue number4
DOIs
Publication statusPublished - 1989
Externally publishedYes

Fingerprint

ion recombination
picosecond pulses
radiolysis
cyclohexane
solutes
liquids
excitation
diffusion theory
absorption spectroscopy
anions
fluorescence
spectroscopy

Cite this

Picosecond pulse radiolysis on geminate ion recombination and formation of solute excited state in liquid cyclohexane. / Yoshida, Y.; Tagawa, S.; Washio, Masakazu; Kobayashi, H.; Tabata, Y.

In: International Journal of Radiation Applications and Instrumentation. Part, Vol. 34, No. 4, 1989, p. 493-496.

Research output: Contribution to journalArticle

@article{5038f85f7b1b44bfb9e91a616d94dc43,
title = "Picosecond pulse radiolysis on geminate ion recombination and formation of solute excited state in liquid cyclohexane",
abstract = "The geminate ion recombination and the formation process of solute excited states in solutions of biphenyl were studied in cyclohexane by means of picosecond pulse radiolysis with absorption and emission spectroscopies. The time-dependent behavior of the biphenyl anion was analyzed with the diffusion theory in the solute-solvent system. By applying this analysis to the time-dependent fluorescence from excited states of biphenyl, yields of the excited states through various formation processes were deduced. Also, yield of excited states of cyclohexane in the absence of solutes was estimated.",
author = "Y. Yoshida and S. Tagawa and Masakazu Washio and H. Kobayashi and Y. Tabata",
year = "1989",
doi = "10.1016/1359-0197(89)90051-9",
language = "English",
volume = "34",
pages = "493--496",
journal = "Radiation Physics and Chemistry",
issn = "0969-806X",
publisher = "Elsevier Limited",
number = "4",

}

TY - JOUR

T1 - Picosecond pulse radiolysis on geminate ion recombination and formation of solute excited state in liquid cyclohexane

AU - Yoshida, Y.

AU - Tagawa, S.

AU - Washio, Masakazu

AU - Kobayashi, H.

AU - Tabata, Y.

PY - 1989

Y1 - 1989

N2 - The geminate ion recombination and the formation process of solute excited states in solutions of biphenyl were studied in cyclohexane by means of picosecond pulse radiolysis with absorption and emission spectroscopies. The time-dependent behavior of the biphenyl anion was analyzed with the diffusion theory in the solute-solvent system. By applying this analysis to the time-dependent fluorescence from excited states of biphenyl, yields of the excited states through various formation processes were deduced. Also, yield of excited states of cyclohexane in the absence of solutes was estimated.

AB - The geminate ion recombination and the formation process of solute excited states in solutions of biphenyl were studied in cyclohexane by means of picosecond pulse radiolysis with absorption and emission spectroscopies. The time-dependent behavior of the biphenyl anion was analyzed with the diffusion theory in the solute-solvent system. By applying this analysis to the time-dependent fluorescence from excited states of biphenyl, yields of the excited states through various formation processes were deduced. Also, yield of excited states of cyclohexane in the absence of solutes was estimated.

UR - http://www.scopus.com/inward/record.url?scp=50849148189&partnerID=8YFLogxK

UR - http://www.scopus.com/inward/citedby.url?scp=50849148189&partnerID=8YFLogxK

U2 - 10.1016/1359-0197(89)90051-9

DO - 10.1016/1359-0197(89)90051-9

M3 - Article

AN - SCOPUS:50849148189

VL - 34

SP - 493

EP - 496

JO - Radiation Physics and Chemistry

JF - Radiation Physics and Chemistry

SN - 0969-806X

IS - 4

ER -