Poly[[4-(N-tert-butyl-N-hydroxyamino)phenyl[acetylene[ and the magnetic property of its radical derivative

Hiroyuki Nishide, Takashi Kaneko, Naoki Yoshioka, Harushisa Akiyama, Masukazu Igarashi, Eishun Tsuchida

Research output: Contribution to journalArticle

38 Citations (Scopus)

Abstract

[4-(N-tert-Butyl-N-hydroxyamino)phenyl]acetylene (7) was synthesized and polymerized to yield a solvent-soluble polyacetylene: poly[[4-(N-tert-butyl-N-hydroxyamino)phenyl ]acetylebe[(8)]. Oxidation of the polymer gave its radical derivative: ESR spectrum showed a broad signal only in the δms = ±1 region, and magnetic measurement with a SQUID magnetometer revealed an antiferromagnetic through-space interaction.

Original languageEnglish
Pages (from-to)4567-4571
Number of pages5
JournalMacromolecules
Volume26
Issue number17
Publication statusPublished - 1993 Jan 1

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Polyacetylenes
SQUIDs
Magnetic variables measurement
Magnetometers
Acetylene
Paramagnetic resonance
Magnetic properties
Polymers
Derivatives
Oxidation
phenylacetylene

ASJC Scopus subject areas

  • Materials Chemistry

Cite this

Nishide, H., Kaneko, T., Yoshioka, N., Akiyama, H., Igarashi, M., & Tsuchida, E. (1993). Poly[[4-(N-tert-butyl-N-hydroxyamino)phenyl[acetylene[ and the magnetic property of its radical derivative. Macromolecules, 26(17), 4567-4571.

Poly[[4-(N-tert-butyl-N-hydroxyamino)phenyl[acetylene[ and the magnetic property of its radical derivative. / Nishide, Hiroyuki; Kaneko, Takashi; Yoshioka, Naoki; Akiyama, Harushisa; Igarashi, Masukazu; Tsuchida, Eishun.

In: Macromolecules, Vol. 26, No. 17, 01.01.1993, p. 4567-4571.

Research output: Contribution to journalArticle

Nishide, H, Kaneko, T, Yoshioka, N, Akiyama, H, Igarashi, M & Tsuchida, E 1993, 'Poly[[4-(N-tert-butyl-N-hydroxyamino)phenyl[acetylene[ and the magnetic property of its radical derivative', Macromolecules, vol. 26, no. 17, pp. 4567-4571.
Nishide H, Kaneko T, Yoshioka N, Akiyama H, Igarashi M, Tsuchida E. Poly[[4-(N-tert-butyl-N-hydroxyamino)phenyl[acetylene[ and the magnetic property of its radical derivative. Macromolecules. 1993 Jan 1;26(17):4567-4571.
Nishide, Hiroyuki ; Kaneko, Takashi ; Yoshioka, Naoki ; Akiyama, Harushisa ; Igarashi, Masukazu ; Tsuchida, Eishun. / Poly[[4-(N-tert-butyl-N-hydroxyamino)phenyl[acetylene[ and the magnetic property of its radical derivative. In: Macromolecules. 1993 ; Vol. 26, No. 17. pp. 4567-4571.
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