Poly[[4-(N-tert-butyl-N-hydroxyamino)phenyl[acetylene[ and the magnetic property of its radical derivative

Hiroyuki Nishide, Takashi Kaneko, Naoki Yoshioka, Harushisa Akiyama, Masukazu Igarashi, Eishun Tsuchida

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Abstract

[4-(N-tert-Butyl-N-hydroxyamino)phenyl]acetylene (7) was synthesized and polymerized to yield a solvent-soluble polyacetylene: poly[[4-(N-tert-butyl-N-hydroxyamino)phenyl ]acetylebe[(8)]. Oxidation of the polymer gave its radical derivative: ESR spectrum showed a broad signal only in the δms = ±1 region, and magnetic measurement with a SQUID magnetometer revealed an antiferromagnetic through-space interaction.

Original languageEnglish
Pages (from-to)4567-4571
Number of pages5
JournalMacromolecules
Volume26
Issue number17
Publication statusPublished - 1993 Jan 1

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ASJC Scopus subject areas

  • Materials Chemistry

Cite this

Nishide, H., Kaneko, T., Yoshioka, N., Akiyama, H., Igarashi, M., & Tsuchida, E. (1993). Poly[[4-(N-tert-butyl-N-hydroxyamino)phenyl[acetylene[ and the magnetic property of its radical derivative. Macromolecules, 26(17), 4567-4571.