POLY(ALKYL METHACRYLATE-METHACRYLATE CARBOXYLATE) ION-CONTAINING BLOCK COPOLYMERS.

Timothy Edward Long; C. D. DePorter; N. Patel; D. W. Dwight; G. L. Wilkes; J. E. McGrath

POLY(ALKYL METHACRYLATE-METHACRYLATE CARBOXYLATE) ION-CONTAINING BLOCK COPOLYMERS.

Timothy Edward Long^*, C. D. DePorter, N. Patel, D. W. Dwight, G. L. Wilkes, J. E. McGrath

^*Corresponding author for this work

Research output: Contribution to journal › Conference article › peer-review

14 Citations (Scopus)

Abstract

All-acrylic block copolymer precursors can be synthesized via anionic techniques demonstrating predictable molecular weights and narrow molecular weight distributions. Poly(2-ethylhexyl methacrylate) can possess such desirable properties as a low glass transition temperature, alkane solubility, and a hydrophobic character. Quantitative hydrolysis of poly(t-butyl methacrylate) blocks allows for very distinct hydrophobic-hydrophilic block copolymers. The derived ion-containing block copolymers will serve as excellent model systems for the elucidation of structure-property relationships. It is believed that the extent and mechanisms of coulombic aggregation will be significantly different than the corresponding random systems.

Original language	English
Pages (from-to)	214-216
Number of pages	3
Journal	American Chemical Society, Polymer Preprints, Division of Polymer Chemistry
Volume	28
Issue number	2
Publication status	Published - 1987 Aug 1
Externally published	Yes
Event	Polym Prepr -Pap Presented at the New Orleans, LA Meet - New Orleans, LA, USA Duration: 1987 Aug 30 → 1987 Sept 4

ASJC Scopus subject areas

Polymers and Plastics

Cite this

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title = "POLY(ALKYL METHACRYLATE-METHACRYLATE CARBOXYLATE) ION-CONTAINING BLOCK COPOLYMERS.",

abstract = "All-acrylic block copolymer precursors can be synthesized via anionic techniques demonstrating predictable molecular weights and narrow molecular weight distributions. Poly(2-ethylhexyl methacrylate) can possess such desirable properties as a low glass transition temperature, alkane solubility, and a hydrophobic character. Quantitative hydrolysis of poly(t-butyl methacrylate) blocks allows for very distinct hydrophobic-hydrophilic block copolymers. The derived ion-containing block copolymers will serve as excellent model systems for the elucidation of structure-property relationships. It is believed that the extent and mechanisms of coulombic aggregation will be significantly different than the corresponding random systems.",

author = "Long, {Timothy Edward} and DePorter, {C. D.} and N. Patel and Dwight, {D. W.} and Wilkes, {G. L.} and McGrath, {J. E.}",

year = "1987",

month = aug,

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language = "English",

volume = "28",

pages = "214--216",

journal = "American Chemical Society, Polymer Preprints, Division of Polymer Chemistry",

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T1 - POLY(ALKYL METHACRYLATE-METHACRYLATE CARBOXYLATE) ION-CONTAINING BLOCK COPOLYMERS.

AU - Long, Timothy Edward

AU - DePorter, C. D.

AU - Patel, N.

AU - Dwight, D. W.

AU - Wilkes, G. L.

AU - McGrath, J. E.

PY - 1987/8/1

Y1 - 1987/8/1

N2 - All-acrylic block copolymer precursors can be synthesized via anionic techniques demonstrating predictable molecular weights and narrow molecular weight distributions. Poly(2-ethylhexyl methacrylate) can possess such desirable properties as a low glass transition temperature, alkane solubility, and a hydrophobic character. Quantitative hydrolysis of poly(t-butyl methacrylate) blocks allows for very distinct hydrophobic-hydrophilic block copolymers. The derived ion-containing block copolymers will serve as excellent model systems for the elucidation of structure-property relationships. It is believed that the extent and mechanisms of coulombic aggregation will be significantly different than the corresponding random systems.

AB - All-acrylic block copolymer precursors can be synthesized via anionic techniques demonstrating predictable molecular weights and narrow molecular weight distributions. Poly(2-ethylhexyl methacrylate) can possess such desirable properties as a low glass transition temperature, alkane solubility, and a hydrophobic character. Quantitative hydrolysis of poly(t-butyl methacrylate) blocks allows for very distinct hydrophobic-hydrophilic block copolymers. The derived ion-containing block copolymers will serve as excellent model systems for the elucidation of structure-property relationships. It is believed that the extent and mechanisms of coulombic aggregation will be significantly different than the corresponding random systems.

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M3 - Conference article

AN - SCOPUS:0042915771

SN - 0032-3934

VL - 28

SP - 214

EP - 216

JO - American Chemical Society, Polymer Preprints, Division of Polymer Chemistry

JF - American Chemical Society, Polymer Preprints, Division of Polymer Chemistry

IS - 2

T2 - Polym Prepr -Pap Presented at the New Orleans, LA Meet

Y2 - 30 August 1987 through 4 September 1987

ER -

POLY(ALKYL METHACRYLATE-METHACRYLATE CARBOXYLATE) ION-CONTAINING BLOCK COPOLYMERS.

Abstract

ASJC Scopus subject areas

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