POLY(ALKYL METHACRYLATE-METHACRYLATE CARBOXYLATE) ION-CONTAINING BLOCK COPOLYMERS.

Timothy Edward Long, C. D. DePorter, N. Patel, D. W. Dwight, G. L. Wilkes, J. E. McGrath

Research output: Contribution to journalConference article

14 Citations (Scopus)

Abstract

All-acrylic block copolymer precursors can be synthesized via anionic techniques demonstrating predictable molecular weights and narrow molecular weight distributions. Poly(2-ethylhexyl methacrylate) can possess such desirable properties as a low glass transition temperature, alkane solubility, and a hydrophobic character. Quantitative hydrolysis of poly(t-butyl methacrylate) blocks allows for very distinct hydrophobic-hydrophilic block copolymers. The derived ion-containing block copolymers will serve as excellent model systems for the elucidation of structure-property relationships. It is believed that the extent and mechanisms of coulombic aggregation will be significantly different than the corresponding random systems.

Original languageEnglish
Pages (from-to)214-216
Number of pages3
JournalAmerican Chemical Society, Polymer Preprints, Division of Polymer Chemistry
Volume28
Issue number2
Publication statusPublished - 1987 Aug 1
Externally publishedYes
EventPolym Prepr -Pap Presented at the New Orleans, LA Meet - New Orleans, LA, USA
Duration: 1987 Aug 301987 Sep 4

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Methacrylates
Block copolymers
Ions
Alkanes
Molecular weight distribution
Paraffins
Acrylics
Hydrolysis
Agglomeration
Solubility
Molecular weight

ASJC Scopus subject areas

  • Polymers and Plastics

Cite this

Long, T. E., DePorter, C. D., Patel, N., Dwight, D. W., Wilkes, G. L., & McGrath, J. E. (1987). POLY(ALKYL METHACRYLATE-METHACRYLATE CARBOXYLATE) ION-CONTAINING BLOCK COPOLYMERS. American Chemical Society, Polymer Preprints, Division of Polymer Chemistry, 28(2), 214-216.

POLY(ALKYL METHACRYLATE-METHACRYLATE CARBOXYLATE) ION-CONTAINING BLOCK COPOLYMERS. / Long, Timothy Edward; DePorter, C. D.; Patel, N.; Dwight, D. W.; Wilkes, G. L.; McGrath, J. E.

In: American Chemical Society, Polymer Preprints, Division of Polymer Chemistry, Vol. 28, No. 2, 01.08.1987, p. 214-216.

Research output: Contribution to journalConference article

Long, TE, DePorter, CD, Patel, N, Dwight, DW, Wilkes, GL & McGrath, JE 1987, 'POLY(ALKYL METHACRYLATE-METHACRYLATE CARBOXYLATE) ION-CONTAINING BLOCK COPOLYMERS.', American Chemical Society, Polymer Preprints, Division of Polymer Chemistry, vol. 28, no. 2, pp. 214-216.
Long, Timothy Edward ; DePorter, C. D. ; Patel, N. ; Dwight, D. W. ; Wilkes, G. L. ; McGrath, J. E. / POLY(ALKYL METHACRYLATE-METHACRYLATE CARBOXYLATE) ION-CONTAINING BLOCK COPOLYMERS. In: American Chemical Society, Polymer Preprints, Division of Polymer Chemistry. 1987 ; Vol. 28, No. 2. pp. 214-216.
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