Abstract
A description of preparation procedure and structure of polymer-metal complexes, which are composed of synthetic polymers and metal ions, is followed by a report on a research program in which several copper-polymer ligand complexes have been used as catalysts in oxidative polymerization of phenol derivatives. Experimental data are tabulated, plotted, and evaluated. It is concluded that, at present, it is not yet possible to predict whether a polymer influences a reaction as catalyst or an inhibitor, because the catalytic mechanism of one reaction differs from another and the rate-determining step varies with the reaction conditions. But at least in the catalysis of the oxidative polymerization of phenols, (1) ease in redox reaction of metal ion, and (2) an interaction between metal ion and oxygen are important to design a catalyst which will exhibit high efficiency and selectivity. Polymers are expected to give positive effects on this approach.
| Original language | English |
|---|---|
| Title of host publication | ACS Symposium Series |
| Publisher | ACS |
| Pages | 147-163 |
| Number of pages | 17 |
| Publication status | Published - 1980 |
| Externally published | Yes |
| Event | ACS Symp Ser 121, Modif of Polym, based on a symp at the ACS (Am Chem Soc)/CSJ (Chem Soc of Jpn) Chem Congr - Honolulu, HI, USA Duration: 1979 Apr 2 → 1979 Apr 6 |
Other
| Other | ACS Symp Ser 121, Modif of Polym, based on a symp at the ACS (Am Chem Soc)/CSJ (Chem Soc of Jpn) Chem Congr |
|---|---|
| City | Honolulu, HI, USA |
| Period | 79/4/2 → 79/4/6 |
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ASJC Scopus subject areas
- Chemistry(all)
Cite this
POLYMER-COPPER CATALYSTS FOR OXIDATIVE POLYMERIZATION OF PHENOL DERIVATIVES. / Tsuchida, E.; Nishide, Hiroyuki.
ACS Symposium Series. ACS, 1980. p. 147-163.Research output: Chapter in Book/Report/Conference proceeding › Chapter
}
TY - CHAP
T1 - POLYMER-COPPER CATALYSTS FOR OXIDATIVE POLYMERIZATION OF PHENOL DERIVATIVES.
AU - Tsuchida, E.
AU - Nishide, Hiroyuki
PY - 1980
Y1 - 1980
N2 - A description of preparation procedure and structure of polymer-metal complexes, which are composed of synthetic polymers and metal ions, is followed by a report on a research program in which several copper-polymer ligand complexes have been used as catalysts in oxidative polymerization of phenol derivatives. Experimental data are tabulated, plotted, and evaluated. It is concluded that, at present, it is not yet possible to predict whether a polymer influences a reaction as catalyst or an inhibitor, because the catalytic mechanism of one reaction differs from another and the rate-determining step varies with the reaction conditions. But at least in the catalysis of the oxidative polymerization of phenols, (1) ease in redox reaction of metal ion, and (2) an interaction between metal ion and oxygen are important to design a catalyst which will exhibit high efficiency and selectivity. Polymers are expected to give positive effects on this approach.
AB - A description of preparation procedure and structure of polymer-metal complexes, which are composed of synthetic polymers and metal ions, is followed by a report on a research program in which several copper-polymer ligand complexes have been used as catalysts in oxidative polymerization of phenol derivatives. Experimental data are tabulated, plotted, and evaluated. It is concluded that, at present, it is not yet possible to predict whether a polymer influences a reaction as catalyst or an inhibitor, because the catalytic mechanism of one reaction differs from another and the rate-determining step varies with the reaction conditions. But at least in the catalysis of the oxidative polymerization of phenols, (1) ease in redox reaction of metal ion, and (2) an interaction between metal ion and oxygen are important to design a catalyst which will exhibit high efficiency and selectivity. Polymers are expected to give positive effects on this approach.
UR - http://www.scopus.com/inward/record.url?scp=0018923784&partnerID=8YFLogxK
UR - http://www.scopus.com/inward/citedby.url?scp=0018923784&partnerID=8YFLogxK
M3 - Chapter
SP - 147
EP - 163
BT - ACS Symposium Series
PB - ACS
ER -