POLYMER-COPPER CATALYSTS FOR OXIDATIVE POLYMERIZATION OF PHENOL DERIVATIVES.

E. Tsuchida, Hiroyuki Nishide

Research output: Chapter in Book/Report/Conference proceedingChapter

5 Citations (Scopus)

Abstract

A description of preparation procedure and structure of polymer-metal complexes, which are composed of synthetic polymers and metal ions, is followed by a report on a research program in which several copper-polymer ligand complexes have been used as catalysts in oxidative polymerization of phenol derivatives. Experimental data are tabulated, plotted, and evaluated. It is concluded that, at present, it is not yet possible to predict whether a polymer influences a reaction as catalyst or an inhibitor, because the catalytic mechanism of one reaction differs from another and the rate-determining step varies with the reaction conditions. But at least in the catalysis of the oxidative polymerization of phenols, (1) ease in redox reaction of metal ion, and (2) an interaction between metal ion and oxygen are important to design a catalyst which will exhibit high efficiency and selectivity. Polymers are expected to give positive effects on this approach.

Original languageEnglish
Title of host publicationACS Symposium Series
PublisherACS
Pages147-163
Number of pages17
Publication statusPublished - 1980
Externally publishedYes
EventACS Symp Ser 121, Modif of Polym, based on a symp at the ACS (Am Chem Soc)/CSJ (Chem Soc of Jpn) Chem Congr - Honolulu, HI, USA
Duration: 1979 Apr 21979 Apr 6

Other

OtherACS Symp Ser 121, Modif of Polym, based on a symp at the ACS (Am Chem Soc)/CSJ (Chem Soc of Jpn) Chem Congr
CityHonolulu, HI, USA
Period79/4/279/4/6

Fingerprint

Phenol
Copper
Polymers
Polymerization
Derivatives
Catalysts
Metal ions
Catalyst selectivity
Redox reactions
Phenols
Coordination Complexes
Catalysis
Oxygen
Ligands

ASJC Scopus subject areas

  • Chemistry(all)

Cite this

Tsuchida, E., & Nishide, H. (1980). POLYMER-COPPER CATALYSTS FOR OXIDATIVE POLYMERIZATION OF PHENOL DERIVATIVES. In ACS Symposium Series (pp. 147-163). ACS.

POLYMER-COPPER CATALYSTS FOR OXIDATIVE POLYMERIZATION OF PHENOL DERIVATIVES. / Tsuchida, E.; Nishide, Hiroyuki.

ACS Symposium Series. ACS, 1980. p. 147-163.

Research output: Chapter in Book/Report/Conference proceedingChapter

Tsuchida, E & Nishide, H 1980, POLYMER-COPPER CATALYSTS FOR OXIDATIVE POLYMERIZATION OF PHENOL DERIVATIVES. in ACS Symposium Series. ACS, pp. 147-163, ACS Symp Ser 121, Modif of Polym, based on a symp at the ACS (Am Chem Soc)/CSJ (Chem Soc of Jpn) Chem Congr, Honolulu, HI, USA, 79/4/2.
Tsuchida E, Nishide H. POLYMER-COPPER CATALYSTS FOR OXIDATIVE POLYMERIZATION OF PHENOL DERIVATIVES. In ACS Symposium Series. ACS. 1980. p. 147-163
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