Abstract
A polymer-metal complex is composed of a synthetic polymer and metal ions. Its synthesis represents an attempt to give an organic polymer inorganic functions. Catalytically active polymers can be obtained by inducing a metal complex to catalyze a reaction with a polymer backbone, and it is reasonable to assume that the metal complex bound to the polymer will show a specific type of catalytic behavior, reflecting the properties of the polymer chain. Indeed, many synthetic polymer-metal complexes have been found to exhibit high catalytic efficiency. This bibliography-based review discusses the subject under headings - formation of structure of pendant-type polymer-metal complexes; formation and stability of polymer chelates; reactivity of polymer-cobalt complexes; reaction of polymer-heme complexes with molecular oxygen; reactions catalyzed by polymer-copper complexes.
| Original language | English |
|---|---|
| Pages (from-to) | 1-87 |
| Number of pages | 87 |
| Journal | Adv Polym Sci |
| Issue number | 24 |
| Publication status | Published - 1977 |
| Externally published | Yes |
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ASJC Scopus subject areas
- Materials Chemistry
- Polymers and Plastics
Cite this
POLYMER-METAL COMPLEXES AND THEIR CATALYTIC ACTIVITY. / Tsuchida, Eishun; Nishide, Hiroyuki.
In: Adv Polym Sci, No. 24, 1977, p. 1-87.Research output: Contribution to journal › Article
}
TY - JOUR
T1 - POLYMER-METAL COMPLEXES AND THEIR CATALYTIC ACTIVITY.
AU - Tsuchida, Eishun
AU - Nishide, Hiroyuki
PY - 1977
Y1 - 1977
N2 - A polymer-metal complex is composed of a synthetic polymer and metal ions. Its synthesis represents an attempt to give an organic polymer inorganic functions. Catalytically active polymers can be obtained by inducing a metal complex to catalyze a reaction with a polymer backbone, and it is reasonable to assume that the metal complex bound to the polymer will show a specific type of catalytic behavior, reflecting the properties of the polymer chain. Indeed, many synthetic polymer-metal complexes have been found to exhibit high catalytic efficiency. This bibliography-based review discusses the subject under headings - formation of structure of pendant-type polymer-metal complexes; formation and stability of polymer chelates; reactivity of polymer-cobalt complexes; reaction of polymer-heme complexes with molecular oxygen; reactions catalyzed by polymer-copper complexes.
AB - A polymer-metal complex is composed of a synthetic polymer and metal ions. Its synthesis represents an attempt to give an organic polymer inorganic functions. Catalytically active polymers can be obtained by inducing a metal complex to catalyze a reaction with a polymer backbone, and it is reasonable to assume that the metal complex bound to the polymer will show a specific type of catalytic behavior, reflecting the properties of the polymer chain. Indeed, many synthetic polymer-metal complexes have been found to exhibit high catalytic efficiency. This bibliography-based review discusses the subject under headings - formation of structure of pendant-type polymer-metal complexes; formation and stability of polymer chelates; reactivity of polymer-cobalt complexes; reaction of polymer-heme complexes with molecular oxygen; reactions catalyzed by polymer-copper complexes.
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UR - http://www.scopus.com/inward/citedby.url?scp=0017561402&partnerID=8YFLogxK
M3 - Article
AN - SCOPUS:0017561402
SP - 1
EP - 87
JO - Advances in Polymer Science
JF - Advances in Polymer Science
SN - 0065-3195
IS - 24
ER -