POLYMER-METAL COMPLEXES AND THEIR CATALYTIC ACTIVITY.

Eishun Tsuchida, Hiroyuki Nishide

Research output: Contribution to journalArticle

200 Citations (Scopus)

Abstract

A polymer-metal complex is composed of a synthetic polymer and metal ions. Its synthesis represents an attempt to give an organic polymer inorganic functions. Catalytically active polymers can be obtained by inducing a metal complex to catalyze a reaction with a polymer backbone, and it is reasonable to assume that the metal complex bound to the polymer will show a specific type of catalytic behavior, reflecting the properties of the polymer chain. Indeed, many synthetic polymer-metal complexes have been found to exhibit high catalytic efficiency. This bibliography-based review discusses the subject under headings - formation of structure of pendant-type polymer-metal complexes; formation and stability of polymer chelates; reactivity of polymer-cobalt complexes; reaction of polymer-heme complexes with molecular oxygen; reactions catalyzed by polymer-copper complexes.

Original languageEnglish
Pages (from-to)1-87
Number of pages87
JournalAdv Polym Sci
Issue number24
Publication statusPublished - 1977
Externally publishedYes

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Coordination Complexes
Metal complexes
Catalyst activity
Polymers
Organic polymers
Molecular oxygen
Bibliographies
Cobalt
Heme
Metal ions
Copper

ASJC Scopus subject areas

  • Materials Chemistry
  • Polymers and Plastics

Cite this

POLYMER-METAL COMPLEXES AND THEIR CATALYTIC ACTIVITY. / Tsuchida, Eishun; Nishide, Hiroyuki.

In: Adv Polym Sci, No. 24, 1977, p. 1-87.

Research output: Contribution to journalArticle

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