Practical conversion of chlorosilanes into alkoxysilanes without generating HCl

Ryutaro Wakabayashi, Yasushi Sugiura, Toshimichi Shibue, Kazuyuki Kuroda

    Research output: Contribution to journalArticle

    21 Citations (Scopus)

    Abstract

    Alcohol-free: A versatile, efficient, and practical synthesis of alkoxysilanes without generation of HCl involves the reaction of chlorosilanes with unsymmetrical ethers in the presence of a Lewis acid (see scheme). The reaction proceeds through selective cleavage of C-O bonds and is superior to conventional processes. Industrially feasible reagents are used and only one by-product results.

    Original languageEnglish
    Pages (from-to)10708-10711
    Number of pages4
    JournalAngewandte Chemie - International Edition
    Volume50
    Issue number45
    DOIs
    Publication statusPublished - 2011 Nov 4

    Fingerprint

    Lewis Acids
    Ethers
    Byproducts
    Alcohols
    Acids

    Keywords

    • ethers
    • lewis acids
    • reaction mechanisms
    • silanes
    • synthetic methods

    ASJC Scopus subject areas

    • Chemistry(all)
    • Catalysis

    Cite this

    Practical conversion of chlorosilanes into alkoxysilanes without generating HCl. / Wakabayashi, Ryutaro; Sugiura, Yasushi; Shibue, Toshimichi; Kuroda, Kazuyuki.

    In: Angewandte Chemie - International Edition, Vol. 50, No. 45, 04.11.2011, p. 10708-10711.

    Research output: Contribution to journalArticle

    Wakabayashi, Ryutaro ; Sugiura, Yasushi ; Shibue, Toshimichi ; Kuroda, Kazuyuki. / Practical conversion of chlorosilanes into alkoxysilanes without generating HCl. In: Angewandte Chemie - International Edition. 2011 ; Vol. 50, No. 45. pp. 10708-10711.
    @article{a8fc79c1af8444579b43bce2aa2df369,
    title = "Practical conversion of chlorosilanes into alkoxysilanes without generating HCl",
    abstract = "Alcohol-free: A versatile, efficient, and practical synthesis of alkoxysilanes without generation of HCl involves the reaction of chlorosilanes with unsymmetrical ethers in the presence of a Lewis acid (see scheme). The reaction proceeds through selective cleavage of C-O bonds and is superior to conventional processes. Industrially feasible reagents are used and only one by-product results.",
    keywords = "ethers, lewis acids, reaction mechanisms, silanes, synthetic methods",
    author = "Ryutaro Wakabayashi and Yasushi Sugiura and Toshimichi Shibue and Kazuyuki Kuroda",
    year = "2011",
    month = "11",
    day = "4",
    doi = "10.1002/anie.201104948",
    language = "English",
    volume = "50",
    pages = "10708--10711",
    journal = "Angewandte Chemie - International Edition",
    issn = "1433-7851",
    publisher = "John Wiley and Sons Ltd",
    number = "45",

    }

    TY - JOUR

    T1 - Practical conversion of chlorosilanes into alkoxysilanes without generating HCl

    AU - Wakabayashi, Ryutaro

    AU - Sugiura, Yasushi

    AU - Shibue, Toshimichi

    AU - Kuroda, Kazuyuki

    PY - 2011/11/4

    Y1 - 2011/11/4

    N2 - Alcohol-free: A versatile, efficient, and practical synthesis of alkoxysilanes without generation of HCl involves the reaction of chlorosilanes with unsymmetrical ethers in the presence of a Lewis acid (see scheme). The reaction proceeds through selective cleavage of C-O bonds and is superior to conventional processes. Industrially feasible reagents are used and only one by-product results.

    AB - Alcohol-free: A versatile, efficient, and practical synthesis of alkoxysilanes without generation of HCl involves the reaction of chlorosilanes with unsymmetrical ethers in the presence of a Lewis acid (see scheme). The reaction proceeds through selective cleavage of C-O bonds and is superior to conventional processes. Industrially feasible reagents are used and only one by-product results.

    KW - ethers

    KW - lewis acids

    KW - reaction mechanisms

    KW - silanes

    KW - synthetic methods

    UR - http://www.scopus.com/inward/record.url?scp=80155211199&partnerID=8YFLogxK

    UR - http://www.scopus.com/inward/citedby.url?scp=80155211199&partnerID=8YFLogxK

    U2 - 10.1002/anie.201104948

    DO - 10.1002/anie.201104948

    M3 - Article

    C2 - 21932229

    AN - SCOPUS:80155211199

    VL - 50

    SP - 10708

    EP - 10711

    JO - Angewandte Chemie - International Edition

    JF - Angewandte Chemie - International Edition

    SN - 1433-7851

    IS - 45

    ER -