Pre-melting structure transformation of water clusters in nanoporous molecular crystals

Makoto Tadokoro; Yuki Ohata; Yuriko Shimazaki; Kyosuke Isoda; Tomoaki Sugaya

doi:10.1002/cphc.201200414

Pre-melting structure transformation of water clusters in nanoporous molecular crystals

Makoto Tadokoro^*, Yuki Ohata, Yuriko Shimazaki, Kyosuke Isoda, Tomoaki Sugaya

^*Corresponding author for this work

Research output: Contribution to journal › Article › peer-review

5 Citations (Scopus)

Abstract

Water nanotubes are one-dimensional channels of water clusters that exist in nanoporous H-bonded metal-coordination crystals of cobalt(III) complexes and trimesate. It is shown by X-ray crystallography that the pre-melting endothermic peak observed in the ascending differential scanning calorimetry curve results from partial movement of water molecules of the frozen state as a result of a structural transition (see picture).

Original language	English
Pages (from-to)	3267-3270
Number of pages	4
Journal	ChemPhysChem
Volume	13
Issue number	14
DOIs	https://doi.org/10.1002/cphc.201200414
Publication status	Published - 2012 Oct 8
Externally published	Yes

Keywords

crystal growth
phase transitions
porous materials
water clusters
x-ray diffraction

ASJC Scopus subject areas

Physical and Theoretical Chemistry
Atomic and Molecular Physics, and Optics

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10.1002/cphc.201200414

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abstract = "Water nanotubes are one-dimensional channels of water clusters that exist in nanoporous H-bonded metal-coordination crystals of cobalt(III) complexes and trimesate. It is shown by X-ray crystallography that the pre-melting endothermic peak observed in the ascending differential scanning calorimetry curve results from partial movement of water molecules of the frozen state as a result of a structural transition (see picture).",

keywords = "crystal growth, phase transitions, porous materials, water clusters, x-ray diffraction",

author = "Makoto Tadokoro and Yuki Ohata and Yuriko Shimazaki and Kyosuke Isoda and Tomoaki Sugaya",

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language = "English",

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journal = "ChemPhysChem",

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T1 - Pre-melting structure transformation of water clusters in nanoporous molecular crystals

AU - Tadokoro, Makoto

AU - Ohata, Yuki

AU - Shimazaki, Yuriko

AU - Isoda, Kyosuke

AU - Sugaya, Tomoaki

PY - 2012/10/8

Y1 - 2012/10/8

N2 - Water nanotubes are one-dimensional channels of water clusters that exist in nanoporous H-bonded metal-coordination crystals of cobalt(III) complexes and trimesate. It is shown by X-ray crystallography that the pre-melting endothermic peak observed in the ascending differential scanning calorimetry curve results from partial movement of water molecules of the frozen state as a result of a structural transition (see picture).

AB - Water nanotubes are one-dimensional channels of water clusters that exist in nanoporous H-bonded metal-coordination crystals of cobalt(III) complexes and trimesate. It is shown by X-ray crystallography that the pre-melting endothermic peak observed in the ascending differential scanning calorimetry curve results from partial movement of water molecules of the frozen state as a result of a structural transition (see picture).

KW - crystal growth

KW - phase transitions

KW - porous materials

KW - water clusters

KW - x-ray diffraction

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UR - http://www.scopus.com/inward/citedby.url?scp=84866999869&partnerID=8YFLogxK

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DO - 10.1002/cphc.201200414

M3 - Article

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EP - 3270

JO - ChemPhysChem

JF - ChemPhysChem

SN - 1439-4235

IS - 14

ER -

Pre-melting structure transformation of water clusters in nanoporous molecular crystals

Abstract

Keywords

ASJC Scopus subject areas

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