Abstract
Water nanotubes are one-dimensional channels of water clusters that exist in nanoporous H-bonded metal-coordination crystals of cobalt(III) complexes and trimesate. It is shown by X-ray crystallography that the pre-melting endothermic peak observed in the ascending differential scanning calorimetry curve results from partial movement of water molecules of the frozen state as a result of a structural transition (see picture).
| Original language | English |
|---|---|
| Pages (from-to) | 3267-3270 |
| Number of pages | 4 |
| Journal | ChemPhysChem |
| Volume | 13 |
| Issue number | 14 |
| DOIs | |
| Publication status | Published - 2012 Oct 8 |
| Externally published | Yes |
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Keywords
- crystal growth
- phase transitions
- porous materials
- water clusters
- x-ray diffraction
ASJC Scopus subject areas
- Physical and Theoretical Chemistry
- Atomic and Molecular Physics, and Optics
Cite this
Pre-melting structure transformation of water clusters in nanoporous molecular crystals. / Tadokoro, Makoto; Ohata, Yuki; Shimazaki, Yuriko; Isoda, Kyosuke; Sugaya, Tomoaki.
In: ChemPhysChem, Vol. 13, No. 14, 08.10.2012, p. 3267-3270.Research output: Contribution to journal › Article
}
TY - JOUR
T1 - Pre-melting structure transformation of water clusters in nanoporous molecular crystals
AU - Tadokoro, Makoto
AU - Ohata, Yuki
AU - Shimazaki, Yuriko
AU - Isoda, Kyosuke
AU - Sugaya, Tomoaki
PY - 2012/10/8
Y1 - 2012/10/8
N2 - Water nanotubes are one-dimensional channels of water clusters that exist in nanoporous H-bonded metal-coordination crystals of cobalt(III) complexes and trimesate. It is shown by X-ray crystallography that the pre-melting endothermic peak observed in the ascending differential scanning calorimetry curve results from partial movement of water molecules of the frozen state as a result of a structural transition (see picture).
AB - Water nanotubes are one-dimensional channels of water clusters that exist in nanoporous H-bonded metal-coordination crystals of cobalt(III) complexes and trimesate. It is shown by X-ray crystallography that the pre-melting endothermic peak observed in the ascending differential scanning calorimetry curve results from partial movement of water molecules of the frozen state as a result of a structural transition (see picture).
KW - crystal growth
KW - phase transitions
KW - porous materials
KW - water clusters
KW - x-ray diffraction
UR - http://www.scopus.com/inward/record.url?scp=84866999869&partnerID=8YFLogxK
UR - http://www.scopus.com/inward/citedby.url?scp=84866999869&partnerID=8YFLogxK
U2 - 10.1002/cphc.201200414
DO - 10.1002/cphc.201200414
M3 - Article
C2 - 22811396
AN - SCOPUS:84866999869
VL - 13
SP - 3267
EP - 3270
JO - ChemPhysChem
JF - ChemPhysChem
SN - 1439-4235
IS - 14
ER -