Prediction of pressure dependent rate constant for the reaction, SiH4(g)→SiH3(g)+H(g), using RRKM theory aided by ab-initio MO

Nagahiro Saito, Mitsuhito Hirota, Takahiro Ishizaki, Akio Fuwa

    Research output: Contribution to journalArticle

    1 Citation (Scopus)

    Abstract

    The pressure dependent rate constant for the reaction, SiH4(g)→SiH3(g)+H was predicted using the Rice-Ramspger-Kassel-Marcus theory aided by Ab-initio molecular orbital (MO). It was calculated under conditions in which the temperatures were from 600 to 1500 K intervals of 100 K. The Arrhenius type rate expression was shown.

    Original languageEnglish
    Pages (from-to)520-526
    Number of pages7
    JournalNippon Kinzoku Gakkaishi/Journal of the Japan Institute of Metals
    Volume63
    Issue number4
    Publication statusPublished - 1999

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    Molecular orbitals
    Rate constants
    molecular orbitals
    rice
    predictions
    intervals
    Temperature
    temperature

    ASJC Scopus subject areas

    • Metals and Alloys

    Cite this

    Prediction of pressure dependent rate constant for the reaction, SiH4(g)→SiH3(g)+H(g), using RRKM theory aided by ab-initio MO. / Saito, Nagahiro; Hirota, Mitsuhito; Ishizaki, Takahiro; Fuwa, Akio.

    In: Nippon Kinzoku Gakkaishi/Journal of the Japan Institute of Metals, Vol. 63, No. 4, 1999, p. 520-526.

    Research output: Contribution to journalArticle

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