Prediction of pressure dependent rate constant for the reaction, SiH4(g)→SiH3(g)+H(g), using RRKM theory aided by ab-initio MO

Nagahiro Saito, Mitsuhito Hirota, Takahiro Ishizaki, Akio Fuwa

    Research output: Contribution to journalArticle

    1 Citation (Scopus)

    Abstract

    The pressure dependent rate constant for the reaction, SiH4(g)→SiH3(g)+H was predicted using the Rice-Ramspger-Kassel-Marcus theory aided by Ab-initio molecular orbital (MO). It was calculated under conditions in which the temperatures were from 600 to 1500 K intervals of 100 K. The Arrhenius type rate expression was shown.

    Original languageEnglish
    Pages (from-to)520-526
    Number of pages7
    JournalNippon Kinzoku Gakkaishi/Journal of the Japan Institute of Metals
    Volume63
    Issue number4
    Publication statusPublished - 1999

    ASJC Scopus subject areas

    • Metals and Alloys

    Fingerprint Dive into the research topics of 'Prediction of pressure dependent rate constant for the reaction, SiH<sub>4</sub>(g)→SiH<sub>3</sub>(g)+H(g), using RRKM theory aided by ab-initio MO'. Together they form a unique fingerprint.

  • Cite this