Preparation and properties of trans-2-butene-1,4-bis (triphenylphosphonium) -saponite

Yusuke Tanaka, Tomohiko Okada, Makoto Ogawa

Research output: Contribution to journalArticle

1 Citation (Scopus)

Abstract

Intercalation of trans-2-butene-1,4-bis(triphenyl phosphonium) into synthetic saponite (Sumecton SA; cation exchange capacity of 71 meq (100 g clay)-1) was conducted by the cation exchange reaction in aqueous solution. The sample was obtained as powder and thin supported film. Quantitative cation exchange was shown by the chemical composition of the product as well as the amount of the trans-2-butene-1,4- bis(triphenylphosphonium) remaining in the solution. The intercalation compound adsorbed styrene from aqueous solution and exhibited thermal stability (decomposes at higher than 400°C) as shown by the TG-DTA curves recorded in air.

Original languageEnglish
Pages (from-to)157-161
Number of pages5
JournalJournal of Porous Materials
Volume13
Issue number2
DOIs
Publication statusPublished - 2006 Apr

Fingerprint

butenes
Butenes
Cations
Ion exchange
Positive ions
cations
intercalation
preparation
aqueous solutions
Intercalation compounds
Styrene
Intercalation
styrenes
Powders
Differential thermal analysis
clays
Clay
chemical composition
thermal analysis
Thermodynamic stability

Keywords

  • Adsorption
  • Intercalation compound
  • Synthetic saponite
  • Trans-2-butene-1, 4-bis (triphenylphosphonium)

ASJC Scopus subject areas

  • Chemistry (miscellaneous)
  • Physical and Theoretical Chemistry
  • Materials Science(all)
  • Catalysis

Cite this

Preparation and properties of trans-2-butene-1,4-bis (triphenylphosphonium) -saponite. / Tanaka, Yusuke; Okada, Tomohiko; Ogawa, Makoto.

In: Journal of Porous Materials, Vol. 13, No. 2, 04.2006, p. 157-161.

Research output: Contribution to journalArticle

Tanaka, Yusuke ; Okada, Tomohiko ; Ogawa, Makoto. / Preparation and properties of trans-2-butene-1,4-bis (triphenylphosphonium) -saponite. In: Journal of Porous Materials. 2006 ; Vol. 13, No. 2. pp. 157-161.
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