Preparation and pyrolysis of poly(allyl iminoalane-co-ethyl iminoalane)s [HAlN(allyl)]m[HAlNEt]n

Yusuke Mori, Yasuhiro Kumakura, Yoshiyuki Sugahara

Research output: Contribution to journalArticle

6 Citations (Scopus)

Abstract

Poly(allyl iminoalane-co-ethyl iminoalane)s {[HAlN(allyl)]m[HAlNEt]n; Allyl/Et-alanes}, have been prepared by reactions of lithium hydridoaluminate (LiAlH4) with a mixture of allylamine hydrochloride (CH2{double bond, long}CHCH2NH2 · HCl; allylNH2 · HCl) and ethylamine hydrochloride (CH3CH2NH2 · HCl; EtNH2 · HCl) with various allyl/Et ratios. Spectroscopic analyses indicate that Allyl/Et-alane(1/3) (allyl/Et = 1/3) contains octamers possessing Al-H and C-H groups as well as C{double bond, long}C, Al-N, and C-N bonds. The loss of aluminum during pyrolysis of Allyl/Et-alane(1/3) at 1600 °C under an Ar atmosphere is 15%, which is less than the value reported for the pyrolysis of poly(ethyliminoalane) (36%). The suppression can be ascribed to cross-linking reactions involving allyl groups (hydroalumination and polymerization of the allyl groups), judging from infrared (IR) and solid-state nuclear magnetic resonance (NMR) spectroscopy.

Original languageEnglish
Pages (from-to)4289-4296
Number of pages8
JournalJournal of Organometallic Chemistry
Volume691
Issue number20
DOIs
Publication statusPublished - 2006 Oct 1

Keywords

  • Aluminum nitride
  • Hydroalumination
  • Poly(allyl iminoalane-co-ethyl iminoalane)s
  • Precursor
  • Pyrolysis

ASJC Scopus subject areas

  • Biochemistry
  • Physical and Theoretical Chemistry
  • Organic Chemistry
  • Inorganic Chemistry
  • Materials Chemistry

Fingerprint Dive into the research topics of 'Preparation and pyrolysis of poly(allyl iminoalane-co-ethyl iminoalane)s [HAlN(allyl)]<sub>m</sub>[HAlNEt]<sub>n</sub>'. Together they form a unique fingerprint.

  • Cite this