Abstract
A thin membrane of the cobalt-tetraphenylporphyrin (CoTPP) complex with the copolymer of octyl methacrylate and vinylimidazole (OIm) was successfully prepared with the thickness of 80 ∼ 90 nm on a porous support membrane. The cobaltporphyrin-highly loaded membrane showed a high performance in the facilitated transport of oxygen. Homogeneous distribution of the CoTPP throughout the membrane and complexation with the imidazolyl residue of Olm with a 5-coordinated structure are described.
| Original language | English |
|---|---|
| Pages (from-to) | 656-660 |
| Number of pages | 5 |
| Journal | Kobunshi Ronbunshu |
| Volume | 59 |
| Issue number | 10 |
| Publication status | Published - 2002 |
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Keywords
- Cobaltporphyrin
- Facilitated transport
- Membrane
- Nano-structure
- Polyvinylimidazole
ASJC Scopus subject areas
- Polymers and Plastics
- Environmental Science(all)
- Materials Science (miscellaneous)
- Chemical Engineering (miscellaneous)
- Ceramics and Composites
Cite this
Preparation and structure of the thin membrane of polymeric cobaltporphyrin complex. / Shinohara, Hiromi; Nakao, Aiko; Nishide, Hiroyuki.
In: Kobunshi Ronbunshu, Vol. 59, No. 10, 2002, p. 656-660.Research output: Contribution to journal › Article
}
TY - JOUR
T1 - Preparation and structure of the thin membrane of polymeric cobaltporphyrin complex
AU - Shinohara, Hiromi
AU - Nakao, Aiko
AU - Nishide, Hiroyuki
PY - 2002
Y1 - 2002
N2 - A thin membrane of the cobalt-tetraphenylporphyrin (CoTPP) complex with the copolymer of octyl methacrylate and vinylimidazole (OIm) was successfully prepared with the thickness of 80 ∼ 90 nm on a porous support membrane. The cobaltporphyrin-highly loaded membrane showed a high performance in the facilitated transport of oxygen. Homogeneous distribution of the CoTPP throughout the membrane and complexation with the imidazolyl residue of Olm with a 5-coordinated structure are described.
AB - A thin membrane of the cobalt-tetraphenylporphyrin (CoTPP) complex with the copolymer of octyl methacrylate and vinylimidazole (OIm) was successfully prepared with the thickness of 80 ∼ 90 nm on a porous support membrane. The cobaltporphyrin-highly loaded membrane showed a high performance in the facilitated transport of oxygen. Homogeneous distribution of the CoTPP throughout the membrane and complexation with the imidazolyl residue of Olm with a 5-coordinated structure are described.
KW - Cobaltporphyrin
KW - Facilitated transport
KW - Membrane
KW - Nano-structure
KW - Polyvinylimidazole
UR - http://www.scopus.com/inward/record.url?scp=0347298545&partnerID=8YFLogxK
UR - http://www.scopus.com/inward/citedby.url?scp=0347298545&partnerID=8YFLogxK
M3 - Article
VL - 59
SP - 656
EP - 660
JO - Kobunshi Ronbunshu
JF - Kobunshi Ronbunshu
SN - 0386-2186
IS - 10
ER -