Preparation and structure of the thin membrane of polymeric cobaltporphyrin complex

Hiromi Shinohara, Aiko Nakao, Hiroyuki Nishide

Research output: Contribution to journalArticle

2 Citations (Scopus)

Abstract

A thin membrane of the cobalt-tetraphenylporphyrin (CoTPP) complex with the copolymer of octyl methacrylate and vinylimidazole (OIm) was successfully prepared with the thickness of 80 ∼ 90 nm on a porous support membrane. The cobaltporphyrin-highly loaded membrane showed a high performance in the facilitated transport of oxygen. Homogeneous distribution of the CoTPP throughout the membrane and complexation with the imidazolyl residue of Olm with a 5-coordinated structure are described.

Original languageEnglish
Pages (from-to)656-660
Number of pages5
JournalKobunshi Ronbunshu
Volume59
Issue number10
Publication statusPublished - 2002

Fingerprint

membrane
Membranes
Cobalt
cobalt
Methacrylates
Complexation
complexation
Copolymers
Oxygen
oxygen
tetraphenylporphyrin
distribution

Keywords

  • Cobaltporphyrin
  • Facilitated transport
  • Membrane
  • Nano-structure
  • Polyvinylimidazole

ASJC Scopus subject areas

  • Polymers and Plastics
  • Environmental Science(all)
  • Materials Science (miscellaneous)
  • Chemical Engineering (miscellaneous)
  • Ceramics and Composites

Cite this

Preparation and structure of the thin membrane of polymeric cobaltporphyrin complex. / Shinohara, Hiromi; Nakao, Aiko; Nishide, Hiroyuki.

In: Kobunshi Ronbunshu, Vol. 59, No. 10, 2002, p. 656-660.

Research output: Contribution to journalArticle

@article{0b7cda122e294a2899c5910cca76ffeb,
title = "Preparation and structure of the thin membrane of polymeric cobaltporphyrin complex",
abstract = "A thin membrane of the cobalt-tetraphenylporphyrin (CoTPP) complex with the copolymer of octyl methacrylate and vinylimidazole (OIm) was successfully prepared with the thickness of 80 ∼ 90 nm on a porous support membrane. The cobaltporphyrin-highly loaded membrane showed a high performance in the facilitated transport of oxygen. Homogeneous distribution of the CoTPP throughout the membrane and complexation with the imidazolyl residue of Olm with a 5-coordinated structure are described.",
keywords = "Cobaltporphyrin, Facilitated transport, Membrane, Nano-structure, Polyvinylimidazole",
author = "Hiromi Shinohara and Aiko Nakao and Hiroyuki Nishide",
year = "2002",
language = "English",
volume = "59",
pages = "656--660",
journal = "Kobunshi Ronbunshu",
issn = "0386-2186",
publisher = "Society of Polymer Science",
number = "10",

}

TY - JOUR

T1 - Preparation and structure of the thin membrane of polymeric cobaltporphyrin complex

AU - Shinohara, Hiromi

AU - Nakao, Aiko

AU - Nishide, Hiroyuki

PY - 2002

Y1 - 2002

N2 - A thin membrane of the cobalt-tetraphenylporphyrin (CoTPP) complex with the copolymer of octyl methacrylate and vinylimidazole (OIm) was successfully prepared with the thickness of 80 ∼ 90 nm on a porous support membrane. The cobaltporphyrin-highly loaded membrane showed a high performance in the facilitated transport of oxygen. Homogeneous distribution of the CoTPP throughout the membrane and complexation with the imidazolyl residue of Olm with a 5-coordinated structure are described.

AB - A thin membrane of the cobalt-tetraphenylporphyrin (CoTPP) complex with the copolymer of octyl methacrylate and vinylimidazole (OIm) was successfully prepared with the thickness of 80 ∼ 90 nm on a porous support membrane. The cobaltporphyrin-highly loaded membrane showed a high performance in the facilitated transport of oxygen. Homogeneous distribution of the CoTPP throughout the membrane and complexation with the imidazolyl residue of Olm with a 5-coordinated structure are described.

KW - Cobaltporphyrin

KW - Facilitated transport

KW - Membrane

KW - Nano-structure

KW - Polyvinylimidazole

UR - http://www.scopus.com/inward/record.url?scp=0347298545&partnerID=8YFLogxK

UR - http://www.scopus.com/inward/citedby.url?scp=0347298545&partnerID=8YFLogxK

M3 - Article

VL - 59

SP - 656

EP - 660

JO - Kobunshi Ronbunshu

JF - Kobunshi Ronbunshu

SN - 0386-2186

IS - 10

ER -