Preparation and vapor adsorption properties of quaternary diammonium-montmorillonites

Yoko Seki, Tomohiko Okada, Makoto Ogawa

Research output: Contribution to journalArticle

6 Citations (Scopus)

Abstract

Adsorption behavior of water, o-xylene and p-xylene vapor to a series of N,N′-hexamethylalkyldiammonium ions [(CH3)3N+(CnH2n+1)(CH3)3N+; where n = 2,3,6,10] exchanged montmorillonites (Kunipia F from Kunimine Ind. Co., Japan; cation exchange capacity of 119 meq (100 g clay)-1 and BENGEL BLIGHT 11 from Hojun, Japan; cation exchange capacity of 78 meq (100 g clay)-1) was investigated. All the organo-clays examined in the present study adsorbed these gases to show their microporous nature. The adsorbed amounts of water, o-xylene and p-xylene increased as the size of N,N′-hexamethylalkyldiammonium was smaller and as the cation exchange capacity of host was larger, showing possible pore volume engineering.

Original languageEnglish
Pages (from-to)30-35
Number of pages6
JournalMicroporous and Mesoporous Materials
Volume124
Issue number1-3
DOIs
Publication statusPublished - 2009 Aug

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Keywords

  • Adsorption
  • Charge density
  • Diquarternaryammonium cation
  • Montmorillonite
  • Organo-clay

ASJC Scopus subject areas

  • Materials Science(all)
  • Mechanics of Materials
  • Chemistry(all)
  • Condensed Matter Physics

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