Preparation of α-zirconium phosphate from fluorozirconate and phosphoric acid by liquid-phase deposition

Seiichi Tahara; Yoshie Takakura; Yoshiyuki Sugahara

doi:10.1246/cl.2012.555

Preparation of α-zirconium phosphate from fluorozirconate and phosphoric acid by liquid-phase deposition

Seiichi Tahara, Yoshie Takakura, Yoshiyuki Sugahara^*

^*Corresponding author for this work

School of Advanced Science and Engineering

Research output: Contribution to journal › Article › peer-review

9 Citations (Scopus)

Abstract

α-Zirconium phosphate (α-ZrP) was prepared by liquid-phase deposition. Boric acid was added to a solution containing [ZrF ₆] ^2- anions, and phosphoric acid dropwise to cause slow decomposition of [ZrF ₆] ^2- and the subsequent reaction with H ₃PO ₄ to form α-ZrP. X-ray diffraction, scanning electron microscopy, solid-state ³¹P nuclear magnetic resonance spectroscopy, infrared spectroscopy, thermogravimetry, and elemental analyses indicate the formation of single-phase α-ZrP.

Original language	English
Pages (from-to)	555-557
Number of pages	3
Journal	Chemistry Letters
Volume	41
Issue number	5
DOIs	https://doi.org/10.1246/cl.2012.555
Publication status	Published - 2012 May 3

ASJC Scopus subject areas

Chemistry(all)

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title = "Preparation of α-zirconium phosphate from fluorozirconate and phosphoric acid by liquid-phase deposition",

abstract = "α-Zirconium phosphate (α-ZrP) was prepared by liquid-phase deposition. Boric acid was added to a solution containing [ZrF 6] 2- anions, and phosphoric acid dropwise to cause slow decomposition of [ZrF 6] 2- and the subsequent reaction with H 3PO 4 to form α-ZrP. X-ray diffraction, scanning electron microscopy, solid-state 31P nuclear magnetic resonance spectroscopy, infrared spectroscopy, thermogravimetry, and elemental analyses indicate the formation of single-phase α-ZrP.",

author = "Seiichi Tahara and Yoshie Takakura and Yoshiyuki Sugahara",

year = "2012",

month = may,

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doi = "10.1246/cl.2012.555",

language = "English",

volume = "41",

pages = "555--557",

journal = "Chemistry Letters",

issn = "0366-7022",

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T1 - Preparation of α-zirconium phosphate from fluorozirconate and phosphoric acid by liquid-phase deposition

AU - Tahara, Seiichi

AU - Takakura, Yoshie

AU - Sugahara, Yoshiyuki

PY - 2012/5/3

Y1 - 2012/5/3

N2 - α-Zirconium phosphate (α-ZrP) was prepared by liquid-phase deposition. Boric acid was added to a solution containing [ZrF 6] 2- anions, and phosphoric acid dropwise to cause slow decomposition of [ZrF 6] 2- and the subsequent reaction with H 3PO 4 to form α-ZrP. X-ray diffraction, scanning electron microscopy, solid-state 31P nuclear magnetic resonance spectroscopy, infrared spectroscopy, thermogravimetry, and elemental analyses indicate the formation of single-phase α-ZrP.

AB - α-Zirconium phosphate (α-ZrP) was prepared by liquid-phase deposition. Boric acid was added to a solution containing [ZrF 6] 2- anions, and phosphoric acid dropwise to cause slow decomposition of [ZrF 6] 2- and the subsequent reaction with H 3PO 4 to form α-ZrP. X-ray diffraction, scanning electron microscopy, solid-state 31P nuclear magnetic resonance spectroscopy, infrared spectroscopy, thermogravimetry, and elemental analyses indicate the formation of single-phase α-ZrP.

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M3 - Article

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EP - 557

JO - Chemistry Letters

JF - Chemistry Letters

IS - 5

ER -

Preparation of α-zirconium phosphate from fluorozirconate and phosphoric acid by liquid-phase deposition

Abstract

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