Preparation of α-zirconium phosphate from fluorozirconate and phosphoric acid by liquid-phase deposition

Seiichi Tahara, Yoshie Takakura, Yoshiyuki Sugahara

    Research output: Contribution to journalArticle

    8 Citations (Scopus)

    Abstract

    α-Zirconium phosphate (α-ZrP) was prepared by liquid-phase deposition. Boric acid was added to a solution containing [ZrF 6] 2- anions, and phosphoric acid dropwise to cause slow decomposition of [ZrF 6] 2- and the subsequent reaction with H 3PO 4 to form α-ZrP. X-ray diffraction, scanning electron microscopy, solid-state 31P nuclear magnetic resonance spectroscopy, infrared spectroscopy, thermogravimetry, and elemental analyses indicate the formation of single-phase α-ZrP.

    Original languageEnglish
    Pages (from-to)555-557
    Number of pages3
    JournalChemistry Letters
    Volume41
    Issue number5
    DOIs
    Publication statusPublished - 2012

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    Nuclear magnetic resonance spectroscopy
    Anions
    Thermogravimetric analysis
    Infrared spectroscopy
    Decomposition
    X ray diffraction
    Scanning electron microscopy
    Liquids
    phosphoric acid
    zirconium phosphate
    boric acid

    ASJC Scopus subject areas

    • Chemistry(all)

    Cite this

    Preparation of α-zirconium phosphate from fluorozirconate and phosphoric acid by liquid-phase deposition. / Tahara, Seiichi; Takakura, Yoshie; Sugahara, Yoshiyuki.

    In: Chemistry Letters, Vol. 41, No. 5, 2012, p. 555-557.

    Research output: Contribution to journalArticle

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