Preparation of a soluble precursor by an aminolysis reaction of Zr(NEt2)4 and its pyrolytic conversion into ZrN

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    Abstract

    A novel soluble precursor with a Zr-N-Zr backbone structure was prepared by an aminolysis reaction of Zr(NEt2)4 with PriNH2. Pyrolysis of the precursor under NH3-N2 atmospheres led to the formation of ZrN as a main crystalline phase with a ceramic yield of 45.2%. Aggregated particles consisting of very minute particles with diameters of 50-300 nm were obtained.

    Original languageEnglish
    Pages (from-to)138-139
    Number of pages2
    JournalChemistry Letters
    Issue number2
    Publication statusPublished - 2000

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    Pyrolysis
    Crystalline materials

    ASJC Scopus subject areas

    • Chemistry(all)

    Cite this

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    title = "Preparation of a soluble precursor by an aminolysis reaction of Zr(NEt2)4 and its pyrolytic conversion into ZrN",
    abstract = "A novel soluble precursor with a Zr-N-Zr backbone structure was prepared by an aminolysis reaction of Zr(NEt2)4 with PriNH2. Pyrolysis of the precursor under NH3-N2 atmospheres led to the formation of ZrN as a main crystalline phase with a ceramic yield of 45.2{\%}. Aggregated particles consisting of very minute particles with diameters of 50-300 nm were obtained.",
    author = "Fei Cheng and Yoshiyuki Sugahara and Kazuyuki Kuroda",
    year = "2000",
    language = "English",
    pages = "138--139",
    journal = "Chemistry Letters",
    issn = "0366-7022",
    publisher = "Chemical Society of Japan",
    number = "2",

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    TY - JOUR

    T1 - Preparation of a soluble precursor by an aminolysis reaction of Zr(NEt2)4 and its pyrolytic conversion into ZrN

    AU - Cheng, Fei

    AU - Sugahara, Yoshiyuki

    AU - Kuroda, Kazuyuki

    PY - 2000

    Y1 - 2000

    N2 - A novel soluble precursor with a Zr-N-Zr backbone structure was prepared by an aminolysis reaction of Zr(NEt2)4 with PriNH2. Pyrolysis of the precursor under NH3-N2 atmospheres led to the formation of ZrN as a main crystalline phase with a ceramic yield of 45.2%. Aggregated particles consisting of very minute particles with diameters of 50-300 nm were obtained.

    AB - A novel soluble precursor with a Zr-N-Zr backbone structure was prepared by an aminolysis reaction of Zr(NEt2)4 with PriNH2. Pyrolysis of the precursor under NH3-N2 atmospheres led to the formation of ZrN as a main crystalline phase with a ceramic yield of 45.2%. Aggregated particles consisting of very minute particles with diameters of 50-300 nm were obtained.

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    JO - Chemistry Letters

    JF - Chemistry Letters

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