Preparation of an intercalation compound of layered titanic acid H2Ti4O9 with methylene blue

Teruyuki Nakato, Yumiko Iwata, Kazuyuki Kuroda, Chuzo Kato

    Research output: Contribution to journalArticle

    10 Citations (Scopus)

    Abstract

    Intercalation of methylene blue into layered titanic acid H2Ti4O9 was examined by a guest exchange method using a propylammonium-HxTi4O9 intercalation compound as the intermediate. Methylene blue cations were arranged in the interlayer space obliquely to the layer surface. The visible spectrum of the intercalation compound suggested that the methylene blue cations were in an associated state in the interlayer space of H2Ti409. The intercalated methylene blue cations underwent a reversible electrochemical redox reaction in the dark, indicating that intercalation compounds of H2Ti4O9 can be applied to a modified electrode.

    Original languageEnglish
    Pages (from-to)249-256
    Number of pages8
    JournalJournal of Inclusion Phenomena and Molecular Recognition in Chemistry
    Volume13
    Issue number3
    DOIs
    Publication statusPublished - 1992 Jul

    Fingerprint

    Intercalation compounds
    methylene blue
    Methylene Blue
    intercalation
    Cations
    cations
    preparation
    acids
    Acids
    interlayers
    redox reactions
    Redox reactions
    Intercalation
    visible spectrum
    electrodes
    Oxidation-Reduction
    surface layers
    Electrodes

    Keywords

    • intercalation
    • methylene blue
    • Tetratitanate

    ASJC Scopus subject areas

    • Condensed Matter Physics
    • Chemistry(all)

    Cite this

    Preparation of an intercalation compound of layered titanic acid H2Ti4O9 with methylene blue. / Nakato, Teruyuki; Iwata, Yumiko; Kuroda, Kazuyuki; Kato, Chuzo.

    In: Journal of Inclusion Phenomena and Molecular Recognition in Chemistry, Vol. 13, No. 3, 07.1992, p. 249-256.

    Research output: Contribution to journalArticle

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