Abstract
Vinyl polymer thin films having carbazole units were prepared by a new method combining physical vapor deposition and self-assembled monolayer (SAM) techniques. 3-(N-carbazolyl)propyl acrylate monomer was evaporated onto a gold substrate that had a VAZO 56 (DuPont) initiator attached as a SAM. The VAZO initiator was activated by irradiating ultraviolet light after depositing the monomer. Although the polymerization reaction can proceed even without the surface initiator, the SAM was effective in improving the surface smoothness, thermal stability, and film-substrate adhesion as a consequence of the formation of covalent chemical bonds between the film and the substrate. Thermal activation of the initiator was examined for the deposition polymerization of 9-H-carbazole-9-ethylmethacryrate. Substrate heating during the evaporation was not effective for accumulating thin films. On the other hand, performing postdeposition annealing on the film after deposition at room temperature resulted in the formation of a polymer thin film chemically bound to the substrate.
| Original language | English |
|---|---|
| Pages (from-to) | 504-508 |
| Number of pages | 5 |
| Journal | Japanese Journal of Applied Physics, Part 1: Regular Papers and Short Notes and Review Papers |
| Volume | 44 |
| Issue number | 1 B |
| DOIs | |
| Publication status | Published - 2005 Jan |
| Externally published | Yes |
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Keywords
- Carbazole polymer
- Deposition polymerization
- Physical vapor deposition
- Self-assembled monolayer
ASJC Scopus subject areas
- Physics and Astronomy (miscellaneous)
Cite this
Preparation of carbazole polymer thin films chemically bound to substrate surface by physical vapor deposition combined with self-assembled monolayer. / Katsuki, Kiyoi; Bekku, Hiroshi; Kawakami, Akira; Locklin, Jason; Patton, Derek; Tanaka, Kuniaki; Advincula, Rigoberto; Usui, Hiroaki.
In: Japanese Journal of Applied Physics, Part 1: Regular Papers and Short Notes and Review Papers, Vol. 44, No. 1 B, 01.2005, p. 504-508.Research output: Contribution to journal › Article
}
TY - JOUR
T1 - Preparation of carbazole polymer thin films chemically bound to substrate surface by physical vapor deposition combined with self-assembled monolayer
AU - Katsuki, Kiyoi
AU - Bekku, Hiroshi
AU - Kawakami, Akira
AU - Locklin, Jason
AU - Patton, Derek
AU - Tanaka, Kuniaki
AU - Advincula, Rigoberto
AU - Usui, Hiroaki
PY - 2005/1
Y1 - 2005/1
N2 - Vinyl polymer thin films having carbazole units were prepared by a new method combining physical vapor deposition and self-assembled monolayer (SAM) techniques. 3-(N-carbazolyl)propyl acrylate monomer was evaporated onto a gold substrate that had a VAZO 56 (DuPont) initiator attached as a SAM. The VAZO initiator was activated by irradiating ultraviolet light after depositing the monomer. Although the polymerization reaction can proceed even without the surface initiator, the SAM was effective in improving the surface smoothness, thermal stability, and film-substrate adhesion as a consequence of the formation of covalent chemical bonds between the film and the substrate. Thermal activation of the initiator was examined for the deposition polymerization of 9-H-carbazole-9-ethylmethacryrate. Substrate heating during the evaporation was not effective for accumulating thin films. On the other hand, performing postdeposition annealing on the film after deposition at room temperature resulted in the formation of a polymer thin film chemically bound to the substrate.
AB - Vinyl polymer thin films having carbazole units were prepared by a new method combining physical vapor deposition and self-assembled monolayer (SAM) techniques. 3-(N-carbazolyl)propyl acrylate monomer was evaporated onto a gold substrate that had a VAZO 56 (DuPont) initiator attached as a SAM. The VAZO initiator was activated by irradiating ultraviolet light after depositing the monomer. Although the polymerization reaction can proceed even without the surface initiator, the SAM was effective in improving the surface smoothness, thermal stability, and film-substrate adhesion as a consequence of the formation of covalent chemical bonds between the film and the substrate. Thermal activation of the initiator was examined for the deposition polymerization of 9-H-carbazole-9-ethylmethacryrate. Substrate heating during the evaporation was not effective for accumulating thin films. On the other hand, performing postdeposition annealing on the film after deposition at room temperature resulted in the formation of a polymer thin film chemically bound to the substrate.
KW - Carbazole polymer
KW - Deposition polymerization
KW - Physical vapor deposition
KW - Self-assembled monolayer
UR - http://www.scopus.com/inward/record.url?scp=17044379014&partnerID=8YFLogxK
UR - http://www.scopus.com/inward/citedby.url?scp=17044379014&partnerID=8YFLogxK
U2 - 10.1143/JJAP.44.504
DO - 10.1143/JJAP.44.504
M3 - Article
AN - SCOPUS:17044379014
VL - 44
SP - 504
EP - 508
JO - Japanese Journal of Applied Physics, Part 1: Regular Papers & Short Notes
JF - Japanese Journal of Applied Physics, Part 1: Regular Papers & Short Notes
SN - 0021-4922
IS - 1 B
ER -