Preparation of CO2-adsorbable amine-functionalized polysilsesquioxanes containing cross-linked structures without using surfactants and strong acid or base catalysts

Yusaku Sainohira, Koki Fujino, Atsushi Shimojima, Kazuyuki Kuroda, Yoshiro Kaneko

Research output: Contribution to journalArticle

Abstract

In this study, we prepared a series of amine-functionalized polysilsesquioxanes (PSQs) containing cross-linked structures via the hydrolytic condensation of mixtures of amino-group-containing organotrialkoxysilanes and bridged organoalkoxysilanes in water under CO2 gas bubbling, followed by lyophilization and heat treatment at 120 °C for 4 h. Among the resulting materials, the amine-functionalized PSQ (PSQ-Am-CL-0.67) prepared from a mixture of 3-aminopropyltrimethoxysilane and bis[3-(trimethoxysilyl)propyl]amine (molar ratio 1:1) as the starting materials in CO2-gas-bubbling water with a solution concentration of 0.67 mol/L exhibited relatively high CO2 adsorption capacity under dry conditions (2.30 mmol(CO2)/g(material)). Moreover, even after repeating the adsorption and desorption of CO2 10 times, the CO2 adsorption capacity of PSQ-Am-CL-0.67 did not noticeably reduce, indicating that it could be used repeatedly as a CO2 capture material. [Figure not available: see fulltext.].

Original languageEnglish
Pages (from-to)505-513
Number of pages9
JournalJournal of Sol-Gel Science and Technology
Volume91
Issue number3
DOIs
Publication statusPublished - 2019 Sep 15

Fingerprint

Surface-Active Agents
Amines
amines
Surface active agents
surfactants
catalysts
preparation
acids
Catalysts
Acids
Adsorption
Gases
Water
adsorption
colloiding
Condensation
Desorption
Heat treatment
polysilsesquioxane
gases

Keywords

  • Carbon dioxide adsorption
  • Hydrolytic condensation
  • Polysilsesquioxane
  • Porous material

ASJC Scopus subject areas

  • Electronic, Optical and Magnetic Materials
  • Ceramics and Composites
  • Chemistry(all)
  • Biomaterials
  • Condensed Matter Physics
  • Materials Chemistry

Cite this

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title = "Preparation of CO2-adsorbable amine-functionalized polysilsesquioxanes containing cross-linked structures without using surfactants and strong acid or base catalysts",
abstract = "In this study, we prepared a series of amine-functionalized polysilsesquioxanes (PSQs) containing cross-linked structures via the hydrolytic condensation of mixtures of amino-group-containing organotrialkoxysilanes and bridged organoalkoxysilanes in water under CO2 gas bubbling, followed by lyophilization and heat treatment at 120 °C for 4 h. Among the resulting materials, the amine-functionalized PSQ (PSQ-Am-CL-0.67) prepared from a mixture of 3-aminopropyltrimethoxysilane and bis[3-(trimethoxysilyl)propyl]amine (molar ratio 1:1) as the starting materials in CO2-gas-bubbling water with a solution concentration of 0.67 mol/L exhibited relatively high CO2 adsorption capacity under dry conditions (2.30 mmol(CO2)/g(material)). Moreover, even after repeating the adsorption and desorption of CO2 10 times, the CO2 adsorption capacity of PSQ-Am-CL-0.67 did not noticeably reduce, indicating that it could be used repeatedly as a CO2 capture material. [Figure not available: see fulltext.].",
keywords = "Carbon dioxide adsorption, Hydrolytic condensation, Polysilsesquioxane, Porous material",
author = "Yusaku Sainohira and Koki Fujino and Atsushi Shimojima and Kazuyuki Kuroda and Yoshiro Kaneko",
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TY - JOUR

T1 - Preparation of CO2-adsorbable amine-functionalized polysilsesquioxanes containing cross-linked structures without using surfactants and strong acid or base catalysts

AU - Sainohira, Yusaku

AU - Fujino, Koki

AU - Shimojima, Atsushi

AU - Kuroda, Kazuyuki

AU - Kaneko, Yoshiro

PY - 2019/9/15

Y1 - 2019/9/15

N2 - In this study, we prepared a series of amine-functionalized polysilsesquioxanes (PSQs) containing cross-linked structures via the hydrolytic condensation of mixtures of amino-group-containing organotrialkoxysilanes and bridged organoalkoxysilanes in water under CO2 gas bubbling, followed by lyophilization and heat treatment at 120 °C for 4 h. Among the resulting materials, the amine-functionalized PSQ (PSQ-Am-CL-0.67) prepared from a mixture of 3-aminopropyltrimethoxysilane and bis[3-(trimethoxysilyl)propyl]amine (molar ratio 1:1) as the starting materials in CO2-gas-bubbling water with a solution concentration of 0.67 mol/L exhibited relatively high CO2 adsorption capacity under dry conditions (2.30 mmol(CO2)/g(material)). Moreover, even after repeating the adsorption and desorption of CO2 10 times, the CO2 adsorption capacity of PSQ-Am-CL-0.67 did not noticeably reduce, indicating that it could be used repeatedly as a CO2 capture material. [Figure not available: see fulltext.].

AB - In this study, we prepared a series of amine-functionalized polysilsesquioxanes (PSQs) containing cross-linked structures via the hydrolytic condensation of mixtures of amino-group-containing organotrialkoxysilanes and bridged organoalkoxysilanes in water under CO2 gas bubbling, followed by lyophilization and heat treatment at 120 °C for 4 h. Among the resulting materials, the amine-functionalized PSQ (PSQ-Am-CL-0.67) prepared from a mixture of 3-aminopropyltrimethoxysilane and bis[3-(trimethoxysilyl)propyl]amine (molar ratio 1:1) as the starting materials in CO2-gas-bubbling water with a solution concentration of 0.67 mol/L exhibited relatively high CO2 adsorption capacity under dry conditions (2.30 mmol(CO2)/g(material)). Moreover, even after repeating the adsorption and desorption of CO2 10 times, the CO2 adsorption capacity of PSQ-Am-CL-0.67 did not noticeably reduce, indicating that it could be used repeatedly as a CO2 capture material. [Figure not available: see fulltext.].

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