Preparation of electropolymerized film of metalloporphyrins and application to electrocatalysts

Manabu Hoshino, Daisuke Komago, Kenichi Oyaizu, Katsuto Otake, Makoto Yuasa

Research output: Chapter in Book/Report/Conference proceedingConference contribution

Abstract

Processing of conductive polymers generally employ organic solvents such as acetonitrile. This work report electrochemical synthesis of a conductive polymer thin film in surpercritical carbon dioxide (scCO2). Iron 5-(3-thienyl)-10,15,20-triethylporphyrin film synthesized in scCO2 was analyzed by scanning electron microscopy and laser microscopy. It was revealed that the thickness and smoothness of the porphyrin film synthesized in scCO2 was 1/10 of those of the film synthesized in dichloromethane.

Original languageEnglish
Title of host publicationPolymer Preprints, Japan
Pages428
Number of pages1
Volume55
Edition1
Publication statusPublished - 2006
Externally publishedYes
Event55th SPSJ Annual Meeting - Nagoya
Duration: 2006 May 242006 May 26

Other

Other55th SPSJ Annual Meeting
CityNagoya
Period06/5/2406/5/26

Fingerprint

Electrocatalysts
Dichloromethane
Porphyrins
Acetonitrile
Polymer films
Organic solvents
Carbon dioxide
Microscopic examination
Iron
Thin films
Scanning electron microscopy
Lasers
Polymers
Processing

Keywords

  • Electrocatalyst
  • Electropolymerization
  • Porphyrin complex
  • Supercritical carbon dioxide

ASJC Scopus subject areas

  • Engineering(all)

Cite this

Hoshino, M., Komago, D., Oyaizu, K., Otake, K., & Yuasa, M. (2006). Preparation of electropolymerized film of metalloporphyrins and application to electrocatalysts. In Polymer Preprints, Japan (1 ed., Vol. 55, pp. 428)

Preparation of electropolymerized film of metalloporphyrins and application to electrocatalysts. / Hoshino, Manabu; Komago, Daisuke; Oyaizu, Kenichi; Otake, Katsuto; Yuasa, Makoto.

Polymer Preprints, Japan. Vol. 55 1. ed. 2006. p. 428.

Research output: Chapter in Book/Report/Conference proceedingConference contribution

Hoshino, M, Komago, D, Oyaizu, K, Otake, K & Yuasa, M 2006, Preparation of electropolymerized film of metalloporphyrins and application to electrocatalysts. in Polymer Preprints, Japan. 1 edn, vol. 55, pp. 428, 55th SPSJ Annual Meeting, Nagoya, 06/5/24.
Hoshino M, Komago D, Oyaizu K, Otake K, Yuasa M. Preparation of electropolymerized film of metalloporphyrins and application to electrocatalysts. In Polymer Preprints, Japan. 1 ed. Vol. 55. 2006. p. 428
Hoshino, Manabu ; Komago, Daisuke ; Oyaizu, Kenichi ; Otake, Katsuto ; Yuasa, Makoto. / Preparation of electropolymerized film of metalloporphyrins and application to electrocatalysts. Polymer Preprints, Japan. Vol. 55 1. ed. 2006. pp. 428
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