Preparation of finite particles of nitrate forms of layered double hydroxides by pH adjustment with anion exchange resin

Shota Naito, Konomi Nitoh, Andre Ayral, Makoto Ogawa

Research output: Contribution to journalArticle

9 Citations (Scopus)

Abstract

Well-defined finite particles of nitrate forms of layered double hydroxides (MgAl and NiAl types) were successfully synthesized from aqueous solution of metal nitrates by the recently developed pH adjustment method, where hydroxide form ion-exchange resin was used to change a starting acidic solution into basic solution for the hydroxide formation. The interlayer nitrate ion of layered double hydroxide was exchanged with such anions as dodecylsulfate and oleate to form intercalation compounds by conventional anion exchange reactions in aqueous media at room temperature, suggesting potential of the methods as well as the present materials for further study on the applications of LDHs.

Original languageEnglish
Pages (from-to)14414-14418
Number of pages5
JournalIndustrial and Engineering Chemistry Research
Volume51
Issue number44
DOIs
Publication statusPublished - 2012 Nov 7

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Hydroxides
Anion Exchange Resins
Nitrates
Ion exchange
Negative ions
Resins
Anions
Ion Exchange Resins
Intercalation compounds
Ion exchange resins
Oleic Acid
Metals
Ions
hydroxide ion
Temperature

ASJC Scopus subject areas

  • Chemical Engineering(all)
  • Chemistry(all)
  • Industrial and Manufacturing Engineering

Cite this

Preparation of finite particles of nitrate forms of layered double hydroxides by pH adjustment with anion exchange resin. / Naito, Shota; Nitoh, Konomi; Ayral, Andre; Ogawa, Makoto.

In: Industrial and Engineering Chemistry Research, Vol. 51, No. 44, 07.11.2012, p. 14414-14418.

Research output: Contribution to journalArticle

Naito, Shota ; Nitoh, Konomi ; Ayral, Andre ; Ogawa, Makoto. / Preparation of finite particles of nitrate forms of layered double hydroxides by pH adjustment with anion exchange resin. In: Industrial and Engineering Chemistry Research. 2012 ; Vol. 51, No. 44. pp. 14414-14418.
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