Preparation of hydrous cerium oxide-impregnated fibers for the recovery of antimony from aqueous media

Rina Hayakawa; Shoko Naruke; Kunio Fujiwara; Takanobu Sugo; Takashi Kojima; Shigeko Kawai-Noma; Daisuke Umeno; Kyoichi Saito

doi:10.2116/bunsekikagaku.66.853

Preparation of hydrous cerium oxide-impregnated fibers for the recovery of antimony from aqueous media

Rina Hayakawa, Shoko Naruke, Kunio Fujiwara, Takanobu Sugo, Takashi Kojima, Shigeko Kawai-Noma, Daisuke Umeno, Kyoichi Saito^*

^*Corresponding author for this work

Research output: Contribution to journal › Article › peer-review

Abstract

Hydrous cerium oxide was impregnated onto a sufonic-acid-group-containing fiber (SS fiber) prepared by radiation-induced graft polymerization and subsequent chemical modifications. Cerium ions (Ce³⁺) were adsorbed onto SS fiber before the formation of hydrous cerium oxide (H-CeO) via precipitation by a reaction with a sodium hydroxide (NaOH) solution at various NaOH concentrations in the range from 0.001 to 0.1 mol L^–1. The maximum percentage impregnation of H-CeO was 12%. In the batch mode, neither SS fiber nor anion-exchange fiber removed any antimony ions, whereas H-CeO fiber captured antimony ions at a high rate.

Original language	English
Pages (from-to)	853-856
Number of pages	4
Journal	BUNSEKI KAGAKU
Volume	66
Issue number	11
DOIs	https://doi.org/10.2116/bunsekikagaku.66.853
Publication status	Published - 2017
Externally published	Yes

Keywords

Antimony
Fibrous adsorbent
Hydrous cerium oxide
Impregnation
Radiation-induced graft polymerization

ASJC Scopus subject areas

Analytical Chemistry

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10.2116/bunsekikagaku.66.853

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title = "Preparation of hydrous cerium oxide-impregnated fibers for the recovery of antimony from aqueous media",

abstract = "Hydrous cerium oxide was impregnated onto a sufonic-acid-group-containing fiber (SS fiber) prepared by radiation-induced graft polymerization and subsequent chemical modifications. Cerium ions (Ce3+) were adsorbed onto SS fiber before the formation of hydrous cerium oxide (H-CeO) via precipitation by a reaction with a sodium hydroxide (NaOH) solution at various NaOH concentrations in the range from 0.001 to 0.1 mol L–1. The maximum percentage impregnation of H-CeO was 12%. In the batch mode, neither SS fiber nor anion-exchange fiber removed any antimony ions, whereas H-CeO fiber captured antimony ions at a high rate.",

keywords = "Antimony, Fibrous adsorbent, Hydrous cerium oxide, Impregnation, Radiation-induced graft polymerization",

author = "Rina Hayakawa and Shoko Naruke and Kunio Fujiwara and Takanobu Sugo and Takashi Kojima and Shigeko Kawai-Noma and Daisuke Umeno and Kyoichi Saito",

note = "Publisher Copyright: {\textcopyright} 2017 The Japan Society for Analytical Chemistry.",

year = "2017",

doi = "10.2116/bunsekikagaku.66.853",

language = "English",

volume = "66",

pages = "853--856",

journal = "Bunseki Kagaku",

issn = "0525-1931",

publisher = "Japan Society for Analytical Chemistry",

number = "11",

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T1 - Preparation of hydrous cerium oxide-impregnated fibers for the recovery of antimony from aqueous media

AU - Hayakawa, Rina

AU - Naruke, Shoko

AU - Fujiwara, Kunio

AU - Sugo, Takanobu

AU - Kojima, Takashi

AU - Kawai-Noma, Shigeko

AU - Umeno, Daisuke

AU - Saito, Kyoichi

PY - 2017

Y1 - 2017

N2 - Hydrous cerium oxide was impregnated onto a sufonic-acid-group-containing fiber (SS fiber) prepared by radiation-induced graft polymerization and subsequent chemical modifications. Cerium ions (Ce3+) were adsorbed onto SS fiber before the formation of hydrous cerium oxide (H-CeO) via precipitation by a reaction with a sodium hydroxide (NaOH) solution at various NaOH concentrations in the range from 0.001 to 0.1 mol L–1. The maximum percentage impregnation of H-CeO was 12%. In the batch mode, neither SS fiber nor anion-exchange fiber removed any antimony ions, whereas H-CeO fiber captured antimony ions at a high rate.

AB - Hydrous cerium oxide was impregnated onto a sufonic-acid-group-containing fiber (SS fiber) prepared by radiation-induced graft polymerization and subsequent chemical modifications. Cerium ions (Ce3+) were adsorbed onto SS fiber before the formation of hydrous cerium oxide (H-CeO) via precipitation by a reaction with a sodium hydroxide (NaOH) solution at various NaOH concentrations in the range from 0.001 to 0.1 mol L–1. The maximum percentage impregnation of H-CeO was 12%. In the batch mode, neither SS fiber nor anion-exchange fiber removed any antimony ions, whereas H-CeO fiber captured antimony ions at a high rate.

KW - Antimony

KW - Fibrous adsorbent

KW - Hydrous cerium oxide

KW - Impregnation

KW - Radiation-induced graft polymerization

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VL - 66

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EP - 856

JO - Bunseki Kagaku

JF - Bunseki Kagaku

SN - 0525-1931

IS - 11

ER -

Preparation of hydrous cerium oxide-impregnated fibers for the recovery of antimony from aqueous media

Abstract

Keywords

ASJC Scopus subject areas

Access to Document

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