Preparation of imidazolinium salts by the Pd-catalyzed reduction of thioureas with triethylsilane and trialkylsilyl triflate

Takehiko Matsumura, Masahisa Nakada

Research output: Contribution to journalArticlepeer-review

15 Citations (Scopus)

Abstract

A Pd-catalyzed method for the preparation of imidazolinium salts from the corresponding thioureas that could then be used for the synthesis of imidazolium and amidinium salts is described. This method has great potential because all the required reagents are readily available and thioureas are safely converted to their corresponding precursors of NHCs under mild conditions.

Original languageEnglish
Pages (from-to)1412-1415
Number of pages4
JournalTetrahedron Letters
Volume55
Issue number8
DOIs
Publication statusPublished - 2014 Feb 19

Keywords

  • Carbon-sulfur bond cleavage
  • Imidazolinium salt
  • NHC
  • Palladium
  • Thiourea

ASJC Scopus subject areas

  • Biochemistry
  • Drug Discovery
  • Organic Chemistry

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