Abstract
The preparation of imides via the palladium-catalyzed coupling reaction of organostannanes is described. The palladium-catalyzed coupling reaction of aryl-, heteroaryl-, and alkenyl(tributyl)stannanes with methyl N-[methoxy(methylthio)methylene]carbamate in the presence of Cu(I) thiophene-2-carboxylate (CuTC) affords imino ethers, which are converted to the corresponding imides in high yield through acid hydrolysis.
| Original language | English |
|---|---|
| Pages (from-to) | 827-840 |
| Number of pages | 14 |
| Journal | Heterocycles |
| Volume | 87 |
| Issue number | 4 |
| DOIs | |
| Publication status | Published - 2013 |
ASJC Scopus subject areas
- Analytical Chemistry
- Pharmacology
- Organic Chemistry
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Orimoto, K., Tomizawa, T., Namera, Y., Oyama, H., Niwa, T., & Nakada, M. (2013). Preparation of imides via the palladium-catalyzed coupling reaction of organostannanes with methyl n-[methoxy(methylthio)methylene]carbamate. Heterocycles, 87(4), 827-840. https://doi.org/10.3987/COM-13-12662