Preparation of imides via the palladium-catalyzed coupling reaction of organostannanes with methyl n-[methoxy(methylthio)methylene]carbamate

Kohei Orimoto, Takuhei Tomizawa, Yuki Namera, Harufumi Oyama, Takashi Niwa, Masahisa Nakada

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6 Citations (Scopus)

Abstract

The preparation of imides via the palladium-catalyzed coupling reaction of organostannanes is described. The palladium-catalyzed coupling reaction of aryl-, heteroaryl-, and alkenyl(tributyl)stannanes with methyl N-[methoxy(methylthio)methylene]carbamate in the presence of Cu(I) thiophene-2-carboxylate (CuTC) affords imino ethers, which are converted to the corresponding imides in high yield through acid hydrolysis.

Original languageEnglish
Pages (from-to)827-840
Number of pages14
JournalHeterocycles
Volume87
Issue number4
DOIs
Publication statusPublished - 2013 Apr 5

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ASJC Scopus subject areas

  • Analytical Chemistry
  • Pharmacology
  • Organic Chemistry

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