Preparation of imides via the palladium-catalyzed coupling reaction of organostannanes with methyl n-[methoxy(methylthio)methylene]carbamate

Kohei Orimoto; Takuhei Tomizawa; Yuki Namera; Harufumi Oyama; Takashi Niwa; Masahisa Nakada

doi:10.3987/COM-13-12662

Preparation of imides via the palladium-catalyzed coupling reaction of organostannanes with methyl n-[methoxy(methylthio)methylene]carbamate

Kohei Orimoto, Takuhei Tomizawa, Yuki Namera, Harufumi Oyama, Takashi Niwa, Masahisa Nakada

School of Advanced Science and Engineering

Research output: Contribution to journal › Article

6 Citations (Scopus)

Abstract

The preparation of imides via the palladium-catalyzed coupling reaction of organostannanes is described. The palladium-catalyzed coupling reaction of aryl-, heteroaryl-, and alkenyl(tributyl)stannanes with methyl N-[methoxy(methylthio)methylene]carbamate in the presence of Cu(I) thiophene-2-carboxylate (CuTC) affords imino ethers, which are converted to the corresponding imides in high yield through acid hydrolysis.

Original language	English
Pages (from-to)	827-840
Number of pages	14
Journal	Heterocycles
Volume	87
Issue number	4
DOIs	https://doi.org/10.3987/COM-13-12662
Publication status	Published - 2013 Apr 5

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ASJC Scopus subject areas

Analytical Chemistry
Pharmacology
Organic Chemistry

Cite this

Orimoto, K., Tomizawa, T., Namera, Y., Oyama, H., Niwa, T., & Nakada, M. (2013). Preparation of imides via the palladium-catalyzed coupling reaction of organostannanes with methyl n-[methoxy(methylthio)methylene]carbamate. Heterocycles, 87(4), 827-840. https://doi.org/10.3987/COM-13-12662

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AU - Niwa, Takashi

AU - Nakada, Masahisa

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10.3987/COM-13-12662