Preparation of intercalation compounds between V2O5 gel and bipyridyl metal complexes

Teruyuki Nakato, Tsuyoshi Ise, Yoshiyuki Sugahara, Kazuyuki Kuroda, Chuzo Kato

    Research output: Contribution to journalArticle

    18 Citations (Scopus)

    Abstract

    The intercalation of tris-bipyridyl metal complexes (M(bpy)3 2+, M=Ru, Ni, and Co) into the interlayer region of vanadium pentoxide gel (V2O5·nH2O) was confirmed for the first time. The intercalation of the guest species was conducted by the reaction of the complexes with undried V2O5 gel. The saturated amount of adsorbed M(bpy)3 2+ was less than the ion exchange capacity of the V2O5 gel because of bulkiness of M(bpy)3 2+. The transition temperature to orthorhombic V2O5 was higher than that of original V2O5 gel, indicating the stabilization of the layered structure by the intercalation.

    Original languageEnglish
    Pages (from-to)309-315
    Number of pages7
    JournalMaterials Research Bulletin
    Volume26
    Issue number4
    DOIs
    Publication statusPublished - 1991

    Fingerprint

    Intercalation compounds
    2,2'-Dipyridyl
    Coordination Complexes
    Metal complexes
    intercalation
    Gels
    Intercalation
    gels
    preparation
    metals
    Vanadium
    vanadium
    Superconducting transition temperature
    interlayers
    Ion exchange
    Stabilization
    stabilization
    transition temperature
    vanadium pentoxide
    ions

    ASJC Scopus subject areas

    • Ceramics and Composites
    • Materials Chemistry

    Cite this

    Preparation of intercalation compounds between V2O5 gel and bipyridyl metal complexes. / Nakato, Teruyuki; Ise, Tsuyoshi; Sugahara, Yoshiyuki; Kuroda, Kazuyuki; Kato, Chuzo.

    In: Materials Research Bulletin, Vol. 26, No. 4, 1991, p. 309-315.

    Research output: Contribution to journalArticle

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    AU - Kuroda, Kazuyuki

    AU - Kato, Chuzo

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