Preparation of intercalation compounds between V2O5 gel and bipyridyl metal complexes

Teruyuki Nakato, Tsuyoshi Ise, Yoshiyuki Sugahara, Kazuyuki Kuroda, Chuzo Kato

Research output: Contribution to journalArticle

18 Citations (Scopus)

Abstract

The intercalation of tris-bipyridyl metal complexes (M(bpy)32+, M=Ru, Ni, and Co) into the interlayer region of vanadium pentoxide gel (V2O5·nH2O) was confirmed for the first time. The intercalation of the guest species was conducted by the reaction of the complexes with undried V2O5 gel. The saturated amount of adsorbed M(bpy)32+ was less than the ion exchange capacity of the V2O5 gel because of bulkiness of M(bpy)32+. The transition temperature to orthorhombic V2O5 was higher than that of original V2O5 gel, indicating the stabilization of the layered structure by the intercalation.

Original languageEnglish
Pages (from-to)309-315
Number of pages7
JournalMaterials Research Bulletin
Volume26
Issue number4
DOIs
Publication statusPublished - 1991 Apr

ASJC Scopus subject areas

  • Materials Science(all)
  • Condensed Matter Physics
  • Mechanics of Materials
  • Mechanical Engineering

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