Preparation of mesostructured silica-micelle hybrids and their conversion to mesoporous silica modified controllably with immobilized hydrophobic blocks by using triethoxysilyl-terminated PEO-PPO-PEO triblock copolymer

Chihiro Urata, Yasuhiro Tamura, Yusuke Yamauchi, Kazuyuki Kuroda

    Research output: Contribution to journalArticle

    8 Citations (Scopus)

    Abstract

    Mesostructured silica having mesopore surface functionalized with poly(ethylene oxide)20-b-poly(propylene oxide)70-b- poly(ethylene oxide)20 (EO20PO70EO 20, P123) micelles was synthesized by using triethoxysilyl-terminated P123 (TES-P123) with dual functions of templating and surface anchoring. The amount of anchored P123 was controlled by mixing TES-P123 and conventional P123 as a cotemplate and the subsequent removal of the cotemplate by extraction. All the samples show the presence of ordered mesopores after the extraction. Unexpectedly, the d-spacing and the pore size increased after the extraction when the ratio of TES-P123/(TES-P123 + P123) was over 75%, which is explained by an osmotic force caused by anchored P123 swollen with THF during the extraction. To evaluate the stability of anchored P123, ibuprofen was simultaneously incorporated into mesopores during the formation of mesostructured silica. When TES-P123 was exclusively used, the percentage of retained P123 after the extraction of IBU was higher than that found for the case of conventional P123. This approach will open a new way to stabilize assembled amphiphiles in regularly ordered siloxane frameworks.

    Original languageEnglish
    Pages (from-to)3711-3717
    Number of pages7
    JournalJournal of Materials Chemistry
    Volume21
    Issue number11
    DOIs
    Publication statusPublished - 2011 Mar 21

    Fingerprint

    Polyphenylene oxides
    Micelles
    Polyethylene oxides
    Silicon Dioxide
    Block copolymers
    Silica
    Siloxanes
    Polypropylene oxides
    Amphiphiles
    Ibuprofen
    Pore size
    PEO-PPO-PEO

    ASJC Scopus subject areas

    • Materials Chemistry
    • Chemistry(all)

    Cite this

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    title = "Preparation of mesostructured silica-micelle hybrids and their conversion to mesoporous silica modified controllably with immobilized hydrophobic blocks by using triethoxysilyl-terminated PEO-PPO-PEO triblock copolymer",
    abstract = "Mesostructured silica having mesopore surface functionalized with poly(ethylene oxide)20-b-poly(propylene oxide)70-b- poly(ethylene oxide)20 (EO20PO70EO 20, P123) micelles was synthesized by using triethoxysilyl-terminated P123 (TES-P123) with dual functions of templating and surface anchoring. The amount of anchored P123 was controlled by mixing TES-P123 and conventional P123 as a cotemplate and the subsequent removal of the cotemplate by extraction. All the samples show the presence of ordered mesopores after the extraction. Unexpectedly, the d-spacing and the pore size increased after the extraction when the ratio of TES-P123/(TES-P123 + P123) was over 75{\%}, which is explained by an osmotic force caused by anchored P123 swollen with THF during the extraction. To evaluate the stability of anchored P123, ibuprofen was simultaneously incorporated into mesopores during the formation of mesostructured silica. When TES-P123 was exclusively used, the percentage of retained P123 after the extraction of IBU was higher than that found for the case of conventional P123. This approach will open a new way to stabilize assembled amphiphiles in regularly ordered siloxane frameworks.",
    author = "Chihiro Urata and Yasuhiro Tamura and Yusuke Yamauchi and Kazuyuki Kuroda",
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    T1 - Preparation of mesostructured silica-micelle hybrids and their conversion to mesoporous silica modified controllably with immobilized hydrophobic blocks by using triethoxysilyl-terminated PEO-PPO-PEO triblock copolymer

    AU - Urata, Chihiro

    AU - Tamura, Yasuhiro

    AU - Yamauchi, Yusuke

    AU - Kuroda, Kazuyuki

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    AB - Mesostructured silica having mesopore surface functionalized with poly(ethylene oxide)20-b-poly(propylene oxide)70-b- poly(ethylene oxide)20 (EO20PO70EO 20, P123) micelles was synthesized by using triethoxysilyl-terminated P123 (TES-P123) with dual functions of templating and surface anchoring. The amount of anchored P123 was controlled by mixing TES-P123 and conventional P123 as a cotemplate and the subsequent removal of the cotemplate by extraction. All the samples show the presence of ordered mesopores after the extraction. Unexpectedly, the d-spacing and the pore size increased after the extraction when the ratio of TES-P123/(TES-P123 + P123) was over 75%, which is explained by an osmotic force caused by anchored P123 swollen with THF during the extraction. To evaluate the stability of anchored P123, ibuprofen was simultaneously incorporated into mesopores during the formation of mesostructured silica. When TES-P123 was exclusively used, the percentage of retained P123 after the extraction of IBU was higher than that found for the case of conventional P123. This approach will open a new way to stabilize assembled amphiphiles in regularly ordered siloxane frameworks.

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