Preparation of poly(1,4‐phenylene)s by electro‐oxidative polymerization

Kenichi Oyaizu, Kimihisa Yamamoto, Toshio Asada, Hiroyuki Nishide, Eishun Tsuchida

Research output: Contribution to journalArticle

1 Citation (Scopus)

Abstract

The effect of substituents on the electropolymerization of benzene derivatives and the redox properrties of the corresponding polymers were determined using Brown's substituent constants (σ+). Electron‐donating groups lower the oxidation potential by which increase in the current efficiency was observed. However, stabilization of the produced cation radicals by the electron‐donating groups resulted in a decrease in the polymerization efficiency. The appropriate values of σ+ for the efficient polymerization ranged near −1.5.

Original languageEnglish
Pages (from-to)254-257
Number of pages4
JournalPolymers for Advanced Technologies
Volume6
Issue number4
DOIs
Publication statusPublished - 1995

Fingerprint

Benzene Derivatives
Polymerization
Electropolymerization
Cations
Benzene
Polymers
Stabilization
Positive ions
Derivatives
Oxidation
Oxidation-Reduction

Keywords

  • electro‐oxidative polymerization
  • poly(1,4‐phenylene)
  • substituent effect

ASJC Scopus subject areas

  • Polymers and Plastics

Cite this

Preparation of poly(1,4‐phenylene)s by electro‐oxidative polymerization. / Oyaizu, Kenichi; Yamamoto, Kimihisa; Asada, Toshio; Nishide, Hiroyuki; Tsuchida, Eishun.

In: Polymers for Advanced Technologies, Vol. 6, No. 4, 1995, p. 254-257.

Research output: Contribution to journalArticle

Oyaizu, Kenichi ; Yamamoto, Kimihisa ; Asada, Toshio ; Nishide, Hiroyuki ; Tsuchida, Eishun. / Preparation of poly(1,4‐phenylene)s by electro‐oxidative polymerization. In: Polymers for Advanced Technologies. 1995 ; Vol. 6, No. 4. pp. 254-257.
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