Preparation of Polymeric Adsorbents Bearing Diglycolamic Acid Ligands for Rare Earth Elements

Tomohiro Shinozaki, Takeshi Ogata, Ryo Kakinuma, Hirokazu Narita, Chiharu Tokoro, Mikiya Tanaka

    Research output: Contribution to journalArticle

    3 Citations (Scopus)

    Abstract

    We synthesized polymeric adsorbents modified with diglycolamic acid ligands for the recovery of rare earth elements. Styrene, divinylbenzene, and glycidyl methacrylate were copolymerized by suspension polymerization in the presence of diluent mixtures of heptane and toluene. Varying the composition of the diluent mixtures changed the pore characteristics of the polymeric particles; the highest specific surface area (51.2 m2/g) was obtained with mixtures of equal volumes of heptane and toluene. Polymeric adsorbents were prepared by functionalizing the synthesized polymeric particles with amino groups and then diglycolamic acid ligands. The content of the amino groups was almost constant, whereas that of the diglycolamic acid ligands depended on the specific surface area of the adsorbents. The synthesized polymeric adsorbents selectively adsorbed rare earth elements from a solution containing rare earth and base metal ions. The high adsorption rate of the adsorbents was due to their large specific surface area.

    Original languageEnglish
    Pages (from-to)11424-11430
    Number of pages7
    JournalIndustrial and Engineering Chemistry Research
    Volume57
    Issue number33
    DOIs
    Publication statusPublished - 2018 Aug 22

    Fingerprint

    Bearings (structural)
    Rare earth elements
    Adsorbents
    Ligands
    Acids
    Specific surface area
    Heptanes
    divinyl benzene
    Toluene
    Heptane
    Styrene
    Rare earths
    Metal ions
    Suspensions
    Polymerization
    Adsorption
    Recovery
    Chemical analysis

    ASJC Scopus subject areas

    • Chemistry(all)
    • Chemical Engineering(all)
    • Industrial and Manufacturing Engineering

    Cite this

    Preparation of Polymeric Adsorbents Bearing Diglycolamic Acid Ligands for Rare Earth Elements. / Shinozaki, Tomohiro; Ogata, Takeshi; Kakinuma, Ryo; Narita, Hirokazu; Tokoro, Chiharu; Tanaka, Mikiya.

    In: Industrial and Engineering Chemistry Research, Vol. 57, No. 33, 22.08.2018, p. 11424-11430.

    Research output: Contribution to journalArticle

    Shinozaki, Tomohiro ; Ogata, Takeshi ; Kakinuma, Ryo ; Narita, Hirokazu ; Tokoro, Chiharu ; Tanaka, Mikiya. / Preparation of Polymeric Adsorbents Bearing Diglycolamic Acid Ligands for Rare Earth Elements. In: Industrial and Engineering Chemistry Research. 2018 ; Vol. 57, No. 33. pp. 11424-11430.
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    AU - Kakinuma, Ryo

    AU - Narita, Hirokazu

    AU - Tokoro, Chiharu

    AU - Tanaka, Mikiya

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