Preparation of porous pentacoordinate organosilicon frameworks using organoalkoxysilanes and tris-catechol linkers

Masaki Naoe, Hiroki Iwashita, Shohei Saito, Masakazu Koike, Hiroaki Wada, Atsushi Shimojima, Kazuyuki Kuroda

Research output: Contribution to journalArticlepeer-review

Abstract

Nanoporous materials with anionic pentacoordinate organosilicon frameworks were prepared using organoalkoxysilanes, tris-catechol linkers (2,3,6,7,10,11-hexahydroxytriphenylene, HHTP), and primary diamines as a cation source. The products have both microporous and mesoporous frameworks with some crystallinity. Design of novel catalysts, adsorbents, and ionexchangers based on the charged frameworks and various organic substituents will be expected.

Original languageEnglish
Pages (from-to)1075-1077
Number of pages3
JournalChemistry Letters
Volume49
Issue number9
DOIs
Publication statusPublished - 2020 Jun

Keywords

  • Organosilane
  • Pentacoordinate silicon
  • Porous materials

ASJC Scopus subject areas

  • Chemistry(all)

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