Preparation of precursors for aluminum nitride-based ceramic composites from cage-type and cyclic building blocks

Yoshiyuki Sugahara, Hiroaki Nakashima, Seiichi Koyama, Yusuke Mori

Research output: Contribution to journalArticlepeer-review

Abstract

Precursors for nitride-based ceramic composites have been prepared from two types of building blocks, cage-type poly(iminoalane) with Al-N backbones and cyclic poly(silazane) with Si-N backbones. Two combinations of poly(iminoalane) and cyclic poly(silazane) were utilized to prepare precursors. For the combination of poly(isopropyliminoalane) and [MeSi(H)NH]n, two building blocks were connected via dehydrocoupling, while Pt-catalyzed hydrosilylation was utilized for the combination of poly(allyliminoalane-co- ethyliminoalane) and [Me(H)SiNH]n. The ceramic yields of poly(iminoalane)s increased upon reactions with [MeSi(H)NH]n.

Original languageEnglish
Pages (from-to)249-250
Number of pages2
JournalKey Engineering Materials
Volume403
DOIs
Publication statusPublished - 2009

Keywords

  • Aluminum nitride
  • Ceramic composite
  • Polymer-derived ceramics

ASJC Scopus subject areas

  • Materials Science(all)
  • Mechanics of Materials
  • Mechanical Engineering

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