Preparation of precursors for si-b-oc-n ceramics via hydrosilylation of building blocks with cyclic structures

Ken Ichi Fuchigami; Yuko Uchimaru; Yoshiyuki Sugahara

Preparation of precursors for si-b-oc-n ceramics via hydrosilylation of building blocks with cyclic structures

Ken Ichi Fuchigami, Yuko Uchimaru, Yoshiyuki Sugahara^*

^*Corresponding author for this work

School of Advanced Science and Engineering

Research output: Chapter in Book/Report/Conference proceeding › Chapter

Abstract

Precursors for Si-B-O-C-N materials were synthesized via hydrosilylation of B-triallylborazine (AB) with 1,3,5,7-tetramethylcyclotetrasiloxane (TMCyS) in toluene at room temperature (TMCyS/AB = 1, 2, 3, 4). Spectroscopic characterizations suggested that C=C bonds in the allyl group of B-triallylborazine (AB) reacted with the Si-H group of TMCyS. TG analysis up to 1000^oC under Ar revealed that the ceramic yields of all the precursors were equal to or above 75%. Both silicon and boron were lost during the pyrolysis of the precursor with TMCyS/AB = 1. The losses of both silicon and boron were limited for the pyrolysis at 400 and 600^oC, while larger amounts of boron were lost upon pyrolysis at 800 and 1000^oC.

Original language	English
Title of host publication	Design, Processing and Properties of Ceramic Materials from Preceramic Precursors
Publisher	Nova Science Publishers, Inc.
Pages	1-13
Number of pages	13
ISBN (Print)	9781612099958
Publication status	Published - 2011 Dec 1

ASJC Scopus subject areas

Materials Science(all)

Cite this

Preparation of precursors for si-b-oc-n ceramics via hydrosilylation of building blocks with cyclic structures. / Fuchigami, Ken Ichi; Uchimaru, Yuko; Sugahara, Yoshiyuki.

Design, Processing and Properties of Ceramic Materials from Preceramic Precursors. Nova Science Publishers, Inc., 2011. p. 1-13.

Research output: Chapter in Book/Report/Conference proceeding › Chapter

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abstract = "Precursors for Si-B-O-C-N materials were synthesized via hydrosilylation of B-triallylborazine (AB) with 1,3,5,7-tetramethylcyclotetrasiloxane (TMCyS) in toluene at room temperature (TMCyS/AB = 1, 2, 3, 4). Spectroscopic characterizations suggested that C=C bonds in the allyl group of B-triallylborazine (AB) reacted with the Si-H group of TMCyS. TG analysis up to 1000oC under Ar revealed that the ceramic yields of all the precursors were equal to or above 75%. Both silicon and boron were lost during the pyrolysis of the precursor with TMCyS/AB = 1. The losses of both silicon and boron were limited for the pyrolysis at 400 and 600oC, while larger amounts of boron were lost upon pyrolysis at 800 and 1000oC.",

author = "Fuchigami, {Ken Ichi} and Yuko Uchimaru and Yoshiyuki Sugahara",

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AU - Fuchigami, Ken Ichi

AU - Uchimaru, Yuko

AU - Sugahara, Yoshiyuki

PY - 2011/12/1

Y1 - 2011/12/1

N2 - Precursors for Si-B-O-C-N materials were synthesized via hydrosilylation of B-triallylborazine (AB) with 1,3,5,7-tetramethylcyclotetrasiloxane (TMCyS) in toluene at room temperature (TMCyS/AB = 1, 2, 3, 4). Spectroscopic characterizations suggested that C=C bonds in the allyl group of B-triallylborazine (AB) reacted with the Si-H group of TMCyS. TG analysis up to 1000oC under Ar revealed that the ceramic yields of all the precursors were equal to or above 75%. Both silicon and boron were lost during the pyrolysis of the precursor with TMCyS/AB = 1. The losses of both silicon and boron were limited for the pyrolysis at 400 and 600oC, while larger amounts of boron were lost upon pyrolysis at 800 and 1000oC.

AB - Precursors for Si-B-O-C-N materials were synthesized via hydrosilylation of B-triallylborazine (AB) with 1,3,5,7-tetramethylcyclotetrasiloxane (TMCyS) in toluene at room temperature (TMCyS/AB = 1, 2, 3, 4). Spectroscopic characterizations suggested that C=C bonds in the allyl group of B-triallylborazine (AB) reacted with the Si-H group of TMCyS. TG analysis up to 1000oC under Ar revealed that the ceramic yields of all the precursors were equal to or above 75%. Both silicon and boron were lost during the pyrolysis of the precursor with TMCyS/AB = 1. The losses of both silicon and boron were limited for the pyrolysis at 400 and 600oC, while larger amounts of boron were lost upon pyrolysis at 800 and 1000oC.

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M3 - Chapter

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SN - 9781612099958

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BT - Design, Processing and Properties of Ceramic Materials from Preceramic Precursors

PB - Nova Science Publishers, Inc.

ER -

Preparation of precursors for si-b-oc-n ceramics via hydrosilylation of building blocks with cyclic structures

Abstract

ASJC Scopus subject areas

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