Preparation of smectite/dodecyldimethylamine N-oxide intercalation compounds

Makoto Ogawa, Nagayuki Kanaoka, Kazuyuki Kuroda

Research output: Contribution to journalArticle

8 Citations (Scopus)

Abstract

The adsorption of dodecyldimethylamine N-oxide into the interlayer space of Na-saponite was investigated. The Na-saponite/dodecyldimethylamine N-oxide intercalation compounds were prepared as supported and unsupported films. Intercalation compounds with two different arrangements of the intercalated dodecyldimethylamine N-oxide were obtained, depending on the adsorbed amounts. When the adsorbed amount was greater than 400 mmol/100 g of clay, the intercalated dodecyldimethylamine N-oxide took a paraffin type bilayer. On the other hand, the intercalated dodecyldimethylamine N-oxide molecules are thought to arrange as a bimolecular coverage with their alkyl chains parallel to the silicate sheet when the added amount of dodecyldimethylamine N-oxide was 100 mmol/100 g of clay. The coadsorption of tris(2,2′-bipyridine)ruthenium(II) with dodecyldimethylamine N-oxide was achieved. The luminescence characteristics of tris(2,2′-bipyridine)ruthenium(II) revealed that there are certain interactions between the adsorbed tris(2,2′-bipyridine)ruthenium(II) and dodecyldimethylamine N-oxide in the interlayer space of saponite. Since the products have been obtained as highly transparent supported and self-standing films, the intercalation of dodecyldimethylamine N-oxide is a way to control the adsorbed states of cationic dyes on the surface of smectites.

Original languageEnglish
Pages (from-to)6969-6973
Number of pages5
JournalLangmuir
Volume14
Issue number24
Publication statusPublished - 1998 Nov 24

ASJC Scopus subject areas

  • Materials Science(all)
  • Condensed Matter Physics
  • Surfaces and Interfaces
  • Spectroscopy
  • Electrochemistry

Fingerprint Dive into the research topics of 'Preparation of smectite/dodecyldimethylamine N-oxide intercalation compounds'. Together they form a unique fingerprint.

  • Cite this