Methyl, heptyl, and benzyl viologens were intercalated into the interlayer space of vanadium pentoxide gel (V2O5 · nH2O) by ion exchange. Intercalated methyl and benzyl viologens were present in monolayer arrangements in which the viologens lie parallel to the oxide layer. Heptyl viologens were intercalated in a transversal arrangement with respect to the host layer. The difference among those arrangements in the interlayer region was ascribed to the different sizes of the dications used.
ASJC Scopus subject areas
- Colloid and Surface Chemistry
- Physical and Theoretical Chemistry
- Surfaces and Interfaces