Preparation of V2O5 gel-viologen intercalation compounds

Teruyuki Nakato, Ikuo Kato, Kazuyuki Kuroda, Chuzo Kato

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    Abstract

    Methyl, heptyl, and benzyl viologens were intercalated into the interlayer space of vanadium pentoxide gel (V2O5 · nH2O) by ion exchange. Intercalated methyl and benzyl viologens were present in monolayer arrangements in which the viologens lie parallel to the oxide layer. Heptyl viologens were intercalated in a transversal arrangement with respect to the host layer. The difference among those arrangements in the interlayer region was ascribed to the different sizes of the dications used.

    Original languageEnglish
    Pages (from-to)447-451
    Number of pages5
    JournalJournal of Colloid and Interface Science
    Volume133
    Issue number2
    DOIs
    Publication statusPublished - 1989

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    ASJC Scopus subject areas

    • Colloid and Surface Chemistry
    • Physical and Theoretical Chemistry
    • Surfaces and Interfaces

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