Producing titanium by reducing TiCl2-MgCl2 mixed salt with magnesium in the molten state

Akio Fuwa, Satoru Takaya

    Research output: Contribution to journalArticle

    19 Citations (Scopus)

    Abstract

    In the Kroll process for titanium sponge metal production, TiCl4 gas is introduced and reacted with molten magnesium metal via a gas-liquid reduction reaction. The magnesium reduction reaction of the mixed salt of TiCl2-MgCl2 via a liquid-liquid reaction has been investigated and the results are reported in this article. First, the molten mixed salt was synthesized through chlorination reaction of solid titanium sponge placed in molten MgCl2 salt, while TiCl4 gas was bubbled at around 1,173K. Then, the TiCl2-MgCl2 was reacted with molten magnesium at similar temperatures. This proposed magnesium reduction reaction of the TiCl2-MgCl2 in the molten state may be more efficient easier to control, and suitable for realizing continuous titanium production.

    Original languageEnglish
    Pages (from-to)56-60
    Number of pages5
    JournalJOM
    Volume57
    Issue number10
    Publication statusPublished - 2005 Oct

    Fingerprint

    Magnesium Chloride
    Titanium
    Magnesium
    titanium
    Molten materials
    magnesium
    Salts
    salt
    sponge
    Gases
    liquid
    Liquids
    Metals
    metal
    chlorination
    gas
    gas production
    Chlorination
    temperature
    Temperature

    ASJC Scopus subject areas

    • Geochemistry and Petrology
    • Geotechnical Engineering and Engineering Geology
    • Materials Science(all)
    • Metals and Alloys

    Cite this

    Producing titanium by reducing TiCl2-MgCl2 mixed salt with magnesium in the molten state. / Fuwa, Akio; Takaya, Satoru.

    In: JOM, Vol. 57, No. 10, 10.2005, p. 56-60.

    Research output: Contribution to journalArticle

    Fuwa, Akio ; Takaya, Satoru. / Producing titanium by reducing TiCl2-MgCl2 mixed salt with magnesium in the molten state. In: JOM. 2005 ; Vol. 57, No. 10. pp. 56-60.
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