Pt-Catalyzed Enantioselective Cycloisomerization for the Synthesis of Planar-Chiral Ferrocene Derivatives

Takanori Shibata*, Ninna Uno, Tomoya Sasaki, Stephen Kyalo Kanyiva

*Corresponding author for this work

Research output: Contribution to journalArticlepeer-review

35 Citations (Scopus)

Abstract

Enantioselective cycloisomerization of 2-ethynyl-1-ferrocenylbenzene derivatives proceeded by using a chiral cationic platinum catalyst at room temperature. The intramolecular reaction gave planar-chiral naphthalene- and anthracene-fused ferrocene derivatives with high to excellent ee.

Original languageEnglish
Pages (from-to)6266-6272
Number of pages7
JournalJournal of Organic Chemistry
Volume81
Issue number15
DOIs
Publication statusPublished - 2016 Aug 5

ASJC Scopus subject areas

  • Organic Chemistry

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