Pt-Catalyzed Enantioselective Cycloisomerization for the Synthesis of Planar-Chiral Ferrocene Derivatives

Takanori Shibata, Ninna Uno, Tomoya Sasaki, Stephen Kyalo Kanyiva

Research output: Contribution to journalArticle

24 Citations (Scopus)

Abstract

Enantioselective cycloisomerization of 2-ethynyl-1-ferrocenylbenzene derivatives proceeded by using a chiral cationic platinum catalyst at room temperature. The intramolecular reaction gave planar-chiral naphthalene- and anthracene-fused ferrocene derivatives with high to excellent ee.

Original languageEnglish
Pages (from-to)6266-6272
Number of pages7
JournalJournal of Organic Chemistry
Volume81
Issue number15
DOIs
Publication statusPublished - 2016 Aug 5

Fingerprint

Derivatives
Platinum
Catalysts
Temperature
ferrocene
anthracene
naphthalene

ASJC Scopus subject areas

  • Organic Chemistry

Cite this

Pt-Catalyzed Enantioselective Cycloisomerization for the Synthesis of Planar-Chiral Ferrocene Derivatives. / Shibata, Takanori; Uno, Ninna; Sasaki, Tomoya; Kanyiva, Stephen Kyalo.

In: Journal of Organic Chemistry, Vol. 81, No. 15, 05.08.2016, p. 6266-6272.

Research output: Contribution to journalArticle

@article{33781a2c9cf54ab696dd6593740c2640,
title = "Pt-Catalyzed Enantioselective Cycloisomerization for the Synthesis of Planar-Chiral Ferrocene Derivatives",
abstract = "Enantioselective cycloisomerization of 2-ethynyl-1-ferrocenylbenzene derivatives proceeded by using a chiral cationic platinum catalyst at room temperature. The intramolecular reaction gave planar-chiral naphthalene- and anthracene-fused ferrocene derivatives with high to excellent ee.",
author = "Takanori Shibata and Ninna Uno and Tomoya Sasaki and Kanyiva, {Stephen Kyalo}",
year = "2016",
month = "8",
day = "5",
doi = "10.1021/acs.joc.6b00825",
language = "English",
volume = "81",
pages = "6266--6272",
journal = "Journal of Organic Chemistry",
issn = "0022-3263",
publisher = "American Chemical Society",
number = "15",

}

TY - JOUR

T1 - Pt-Catalyzed Enantioselective Cycloisomerization for the Synthesis of Planar-Chiral Ferrocene Derivatives

AU - Shibata, Takanori

AU - Uno, Ninna

AU - Sasaki, Tomoya

AU - Kanyiva, Stephen Kyalo

PY - 2016/8/5

Y1 - 2016/8/5

N2 - Enantioselective cycloisomerization of 2-ethynyl-1-ferrocenylbenzene derivatives proceeded by using a chiral cationic platinum catalyst at room temperature. The intramolecular reaction gave planar-chiral naphthalene- and anthracene-fused ferrocene derivatives with high to excellent ee.

AB - Enantioselective cycloisomerization of 2-ethynyl-1-ferrocenylbenzene derivatives proceeded by using a chiral cationic platinum catalyst at room temperature. The intramolecular reaction gave planar-chiral naphthalene- and anthracene-fused ferrocene derivatives with high to excellent ee.

UR - http://www.scopus.com/inward/record.url?scp=84981164878&partnerID=8YFLogxK

UR - http://www.scopus.com/inward/citedby.url?scp=84981164878&partnerID=8YFLogxK

U2 - 10.1021/acs.joc.6b00825

DO - 10.1021/acs.joc.6b00825

M3 - Article

AN - SCOPUS:84981164878

VL - 81

SP - 6266

EP - 6272

JO - Journal of Organic Chemistry

JF - Journal of Organic Chemistry

SN - 0022-3263

IS - 15

ER -