Pulse radiolysis studies on the transient species of aromatic molecules in chlorinated hydrocarbon solutions

Masakazu Washio; Seiichi Tagawa; Kazuo Furuya; Nariyuki Hayashi; Yoneho Tabata

doi:10.1016/1359-0197(89)90057-X

Pulse radiolysis studies on the transient species of aromatic molecules in chlorinated hydrocarbon solutions

Masakazu Washio^*, Seiichi Tagawa, Kazuo Furuya, Nariyuki Hayashi, Yoneho Tabata

^*Corresponding author for this work

Research output: Contribution to journal › Article › peer-review

4 Citations (Scopus)

Abstract

Pulse radiolysis has been carried out to identify the transient species produced by the pulsed electron irradiation for the several kinds of combination of the solutions of aromatic hydrocarbons (benzene, naphthalene and pyrene) in chlorinated hydrocarbons (CCl₄, CHCl₃, and CH₂Cl₂). Charge-transfer complex between aromatic ring and Cl atom has been observed for benzene solutions in above three solvents. Naphthalene monomer and dimer cation radicals have been observed for the solutions in CHCl₃ and CH₂Cl₂. Monomer cation radicals of pyrene has been observed for the solution of pyrene in CCl₄, and monomer and dimer cation radicals of pyrene have been observed for the solutions in CHCl₃ and CH₂Cl₂.

Original language	English
Pages (from-to)	533-537
Number of pages	5
Journal	International Journal of Radiation Applications and Instrumentation. Part
Volume	34
Issue number	4
DOIs	https://doi.org/10.1016/1359-0197(89)90057-X
Publication status	Published - 1989
Externally published	Yes

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title = "Pulse radiolysis studies on the transient species of aromatic molecules in chlorinated hydrocarbon solutions",

abstract = "Pulse radiolysis has been carried out to identify the transient species produced by the pulsed electron irradiation for the several kinds of combination of the solutions of aromatic hydrocarbons (benzene, naphthalene and pyrene) in chlorinated hydrocarbons (CCl4, CHCl3, and CH2Cl2). Charge-transfer complex between aromatic ring and Cl atom has been observed for benzene solutions in above three solvents. Naphthalene monomer and dimer cation radicals have been observed for the solutions in CHCl3 and CH2Cl2. Monomer cation radicals of pyrene has been observed for the solution of pyrene in CCl4, and monomer and dimer cation radicals of pyrene have been observed for the solutions in CHCl3 and CH2Cl2.",

author = "Masakazu Washio and Seiichi Tagawa and Kazuo Furuya and Nariyuki Hayashi and Yoneho Tabata",

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T1 - Pulse radiolysis studies on the transient species of aromatic molecules in chlorinated hydrocarbon solutions

AU - Washio, Masakazu

AU - Tagawa, Seiichi

AU - Furuya, Kazuo

AU - Hayashi, Nariyuki

AU - Tabata, Yoneho

PY - 1989

Y1 - 1989

N2 - Pulse radiolysis has been carried out to identify the transient species produced by the pulsed electron irradiation for the several kinds of combination of the solutions of aromatic hydrocarbons (benzene, naphthalene and pyrene) in chlorinated hydrocarbons (CCl4, CHCl3, and CH2Cl2). Charge-transfer complex between aromatic ring and Cl atom has been observed for benzene solutions in above three solvents. Naphthalene monomer and dimer cation radicals have been observed for the solutions in CHCl3 and CH2Cl2. Monomer cation radicals of pyrene has been observed for the solution of pyrene in CCl4, and monomer and dimer cation radicals of pyrene have been observed for the solutions in CHCl3 and CH2Cl2.

AB - Pulse radiolysis has been carried out to identify the transient species produced by the pulsed electron irradiation for the several kinds of combination of the solutions of aromatic hydrocarbons (benzene, naphthalene and pyrene) in chlorinated hydrocarbons (CCl4, CHCl3, and CH2Cl2). Charge-transfer complex between aromatic ring and Cl atom has been observed for benzene solutions in above three solvents. Naphthalene monomer and dimer cation radicals have been observed for the solutions in CHCl3 and CH2Cl2. Monomer cation radicals of pyrene has been observed for the solution of pyrene in CCl4, and monomer and dimer cation radicals of pyrene have been observed for the solutions in CHCl3 and CH2Cl2.

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Pulse radiolysis studies on the transient species of aromatic molecules in chlorinated hydrocarbon solutions

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