We have been studying a pump-probe pulse radiolysis as an application of the S-band photo cathode RF-Gun. Pump-probe spectroscopy is well-known method of pulse radiolysis measurement. We had used 5MeV electron beam obtained from the photo cathode RF-Gun as a pump beam, and used the white light emitted from Xe flash lamp or generated by self-phase modulation in the water cell as a probe light. However, the white probe light with high intensity, good stability and broad spectrum is a key issue for pump-probe pulse radiolysis. Supercontinuum light with photonic crystal fiber (PCF) is a new technique of white light generation. Short pulse laser through PCF spreads its spectrum by nonlinear optical effect. Supercontinuum light has very continuous spectrum, and it is studied for various applications recently. For applying supercontinuum light as a probe of pulse radiolysis experiment, we have generated a supercontinuum radiation with 7 picoseconds pulse width IR (1064nm) laser and PCF, and measured its properties. The experimental results of supercontinuum generation and design of a supercontinuum based pulse radiolysis system will be presented.