Pyrolysis of poly(isopropyliminoalane) to aluminum nitride

Research output: Contribution to journalArticle

25 Citations (Scopus)

Abstract

The pyrolysis processes of poly(isopropyliminoalane) ((HAlNiPr)n) were investigated, using mass spectrometry to analyze the gases and infrared spectroscopy to analyze the residual solids. The major mass loss (in the temperature range of 240°-540 °C) consisted of two different pyrolysis stages. At the first stage (240°-320 °C), (HAlNiPr)6 was detected continuously as a gas, and the precursor was converted to a cross-linked structure. A polymerization mechanism without a release of organic compounds has been proposed, and the formation of (HAlNiPr)6 during polymerization (besides its evaporation) has been suggested. The second stage (320°-560 °C) involved the formation of various organic compounds, and radical processes for their formation were proposed.

Original languageEnglish
Pages (from-to)2436-2440
Number of pages5
JournalJournal of the American Ceramic Society
Volume83
Issue number10
Publication statusPublished - 2000 Oct
Externally publishedYes

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Aluminum nitride
Organic compounds
Pyrolysis
Gases
Polymerization
Mass spectrometry
Infrared spectroscopy
Evaporation
Temperature
aluminum nitride

ASJC Scopus subject areas

  • Ceramics and Composites

Cite this

Pyrolysis of poly(isopropyliminoalane) to aluminum nitride. / Saito, Yasuo; Sugahara, Yoshiyuki; Kuroda, Kazuyuki.

In: Journal of the American Ceramic Society, Vol. 83, No. 10, 10.2000, p. 2436-2440.

Research output: Contribution to journalArticle

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