Quadruple hydrogen bonding containing supramolecular thermoplastic elastomers

Mechanical and morphological correlations

Xi Chen, Keren Zhang, Samantha J. Talley, Christina M. Orsino, Robert B. Moore, Timothy Edward Long

Research output: Contribution to journalArticle

Abstract

We report the design of bioinspired, reversible supramolecular thermoplastic elastomers (TPEs) functionalized with ureido-cytosine (UCyt) complementary quadruple hydrogen bonding (QHB) sites. The polymer contained a soft poly(n-butyl acrylate) central block that imparted flexibility and two external, hard nucleobase-containing blocks that contributed to structural integrity. In addition, the hard block with pendant QHB motifs served as efficient physical crosslinks to further enhance the thermomechanical performance, where the polymer service window extended up to 30 °C higher compared to the controls that bear dimeric hydrogen bonding units. The resulting UCyt copolymers also exhibited improved surface and bulk morphology, which self-assembled into well-ordered lamellar microstructures. Moreover, the polymer displayed an unexpected moisture-resistant property with less than 1 wt % equilibrium moisture uptake even at 95% relatively humidity, which presumably correlated with its well-ordered and densely-packed morphology facilitated by strong hydrogen bonding. Variable temperature Fourier-transform infrared spectroscopy experiments further confirmed the thermoreversibility of hydrogen bonding, indicating melt-processablility and recyclability of the polymer. These physical properties verified quadruple bonding dominated behavior, and structure–property–morphology relationships suggest key design parameters for future TPEs.

Original languageEnglish
JournalJournal of Polymer Science, Part A: Polymer Chemistry
DOIs
Publication statusAccepted/In press - 2018 Jan 1
Externally publishedYes

Fingerprint

Thermoplastic elastomers
Hydrogen bonds
Polymers
Cytosine
Moisture
Structural integrity
Fourier transform infrared spectroscopy
Atmospheric humidity
Copolymers
Physical properties
Microstructure
Experiments
Temperature

Keywords

  • block copolymers
  • quadruple hydrogen bonding
  • structure–property–morphology relationships
  • supramolecular polymers
  • ureido-cytosine

ASJC Scopus subject areas

  • Polymers and Plastics
  • Organic Chemistry
  • Materials Chemistry

Cite this

Quadruple hydrogen bonding containing supramolecular thermoplastic elastomers : Mechanical and morphological correlations. / Chen, Xi; Zhang, Keren; Talley, Samantha J.; Orsino, Christina M.; Moore, Robert B.; Long, Timothy Edward.

In: Journal of Polymer Science, Part A: Polymer Chemistry, 01.01.2018.

Research output: Contribution to journalArticle

Chen, Xi ; Zhang, Keren ; Talley, Samantha J. ; Orsino, Christina M. ; Moore, Robert B. ; Long, Timothy Edward. / Quadruple hydrogen bonding containing supramolecular thermoplastic elastomers : Mechanical and morphological correlations. In: Journal of Polymer Science, Part A: Polymer Chemistry. 2018.
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