Raman-active phonons and their doping dependence in spin-ladder Sr14Cu24O41

M. Osada, M. Kakihana, I. Nagai, T. Noji, T. Adachi, Y. Koike, J. Bäckström, M. Käll, L. Börjesson

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6 Citations (Scopus)


Raman spectra of Sr14-xCaxCu24O41 have been investigated in a number of well-defined single-crystal and polycrystalline samples. From the polarization and doping dependence, and from a comparison with previous reports on isostructural compounds, we identify the (4Ag + 4B1g + 3B2g + B3g) modes that are Raman allowed within the simple Fmmm structure, consisting of two Cu-O sub-lattices. With increasing Ca content, we observe the intensity decrease in the modes involving the atoms of the ladders. This effect, analogous to the CuO2-plane phonons in the high-Tc cuprates, can be attributed to the hole transfer from the chains to the ladders.

Original languageEnglish
Pages (from-to)161-165
Number of pages5
JournalPhysica C: Superconductivity and its Applications
Issue number1
Publication statusPublished - 2000 Aug 1
Externally publishedYes

ASJC Scopus subject areas

  • Condensed Matter Physics

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    Osada, M., Kakihana, M., Nagai, I., Noji, T., Adachi, T., Koike, Y., Bäckström, J., Käll, M., & Börjesson, L. (2000). Raman-active phonons and their doping dependence in spin-ladder Sr14Cu24O41. Physica C: Superconductivity and its Applications, 338(1), 161-165. https://doi.org/10.1016/S0921-4534(00)00220-3