Raman spectra of polypyrrole and its 2,5-13C-substituted and C-deuterated analogues in doped and undoped states

Y. Furukawa, S. Tazawa, Y. Fujii, I. Harada

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246 Citations (Scopus)

Abstract

Raman and optical absorption spectra were studied on electrochemically polymerized polypyrrole in as-polymerized doped (highly conductive), partially undoped and substantially undoped 'neutral' (insulating) states. Vibrational assignments were made on the basis of the data of 2,5-13C-substituted and C-deuterated derivatives. The Raman result of the neutral polymer is consistent with the α,α′-linked all-s-trans coplanar and conjugated structure. In the as-polymerized polymer there exist both radical cation and dication in which the bond orders of C3C4 and interring CC are increased as compared to those in the neutral polymer. The structural distortion in the dication is greater than that in the radical cation. Changes in optical absorption and Raman spectra during reduction (undoping) were explained by the conversions of the dication to the radical cation and the radical cation to the neutral species.

Original languageEnglish
Pages (from-to)329-341
Number of pages13
JournalSynthetic Metals
Volume24
Issue number4
DOIs
Publication statusPublished - 1988 Jun

ASJC Scopus subject areas

  • Electronic, Optical and Magnetic Materials
  • Condensed Matter Physics
  • Mechanics of Materials
  • Mechanical Engineering
  • Metals and Alloys
  • Materials Chemistry

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