Raman studies of intact and sodium doped 13C‐substituted poly‐p‐phenylene

Yukio Furukawa, Hirofumi Ohtsuka, Mitsuo Tasumi, Isao Wataru, Takaki Kanbara, Takakazu Yamamoto

Research output: Contribution to journalArticle

18 Citations (Scopus)

Abstract

The Raman and infrared spectra of 13C‐substituted poly‐p‐phenylene (PPP) and the Raman spectra of Na‐doped PPP excited at 488.0 and 1064 nm were observed and compared with the corresponding spectra for the ordinary (12C) polymer. 13C substitution is shown to be useful for characterizing not only the bands of intact PPP but also those of polarons and bipolarons generated in Na‐doped PPP. The number of Raman bands observed for bioplarons (and also for polarons) is greater than that for intact PPP. This observation is explained as the result of the loss of translational symmetry in the regions of these local excitations.

Original languageEnglish
Pages (from-to)551-554
Number of pages4
JournalJournal of Raman Spectroscopy
Volume24
Issue number8
DOIs
Publication statusPublished - 1993
Externally publishedYes

ASJC Scopus subject areas

  • Materials Science(all)
  • Spectroscopy

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