Reaction kinetics of FeO containing molten slags

Kimihisa Ito, Tasuku Hamano, Kenji Matsuzaki

    Research output: Contribution to journalArticle

    Abstract

    The kinetic study of FeO-containing slag is valuable if we consider slag-gas and slag-metal reactions in steelmaking process. In the present work, the reduction rate of FetO-SiO2-TiO2-MOx (MOx = CaO, MgO, AlO1.5, PO2.5) melts in equilibrium with solid iron by CO gas was measured sing the thermobalance system at 1673 K. A rate equation was developed based on the results obtained. The mechanisms of the reaction and the effect of P2O5 as a surfactant were discussed. Solid CaO was reacted with FeO-containing slag at 1573 to 1673 K. The CaO-slag interface was analyzed by SEM and EDX, and the reacted layers were identified. The rate of solid CaO dissolution into a stagnant FeO-containing slag at hot-metal temperatures was explained by the FeO diffusion in slag phase.

    Original languageEnglish
    Pages (from-to)9-13
    Number of pages5
    JournalSteel Research
    Volume74
    Issue number1
    Publication statusPublished - 2003 Jan

    Fingerprint

    slags
    Reaction kinetics
    Slags
    Molten materials
    reaction kinetics
    phosphorus pentoxide
    Gases
    Metals
    thermobalances
    Steelmaking
    Carbon Monoxide
    gases
    Surface-Active Agents
    metals
    Energy dispersive spectroscopy
    dissolving
    Dissolution
    Surface active agents
    Iron
    surfactants

    ASJC Scopus subject areas

    • Metals and Alloys

    Cite this

    Ito, K., Hamano, T., & Matsuzaki, K. (2003). Reaction kinetics of FeO containing molten slags. Steel Research, 74(1), 9-13.

    Reaction kinetics of FeO containing molten slags. / Ito, Kimihisa; Hamano, Tasuku; Matsuzaki, Kenji.

    In: Steel Research, Vol. 74, No. 1, 01.2003, p. 9-13.

    Research output: Contribution to journalArticle

    Ito, K, Hamano, T & Matsuzaki, K 2003, 'Reaction kinetics of FeO containing molten slags', Steel Research, vol. 74, no. 1, pp. 9-13.
    Ito K, Hamano T, Matsuzaki K. Reaction kinetics of FeO containing molten slags. Steel Research. 2003 Jan;74(1):9-13.
    Ito, Kimihisa ; Hamano, Tasuku ; Matsuzaki, Kenji. / Reaction kinetics of FeO containing molten slags. In: Steel Research. 2003 ; Vol. 74, No. 1. pp. 9-13.
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