Reaction of a stable digermyne with acetylenes: Synthesis of a 1,2-digermabenzene and a 1,4-digermabarrelene#

Tomohiro Sugahara, Jing Dong Guo, Takahiro Sasamori, Yusaku Karatsu, Yukio Furukawa, Arturo Espinosa Ferao, Shigeru Nagase, Norihiro Tokitoh

    Research output: Contribution to journalArticle

    20 Citations (Scopus)

    Abstract

    Reactions between acetylenes and a stable digermyne bearing 4-t-Bu-2,6-[CH(SiMe3)2]2-C6H2 (Tbb) groups afforded the corresponding stable 1,2-digermabenzenes together with the respective 1,4-digermabarrelenes. The properties of the obtained products and the reaction mechanism are discussed on the basis of experimental and theoretical results. Especially, the aromaticity of the newly obtained 1,2-digermabenzene has been discussed on the detailed calculations, revealing its aromatic character to some degree.

    Original languageEnglish
    Pages (from-to)1375-1384
    Number of pages10
    JournalBulletin of the Chemical Society of Japan
    Volume89
    Issue number11
    DOIs
    Publication statusPublished - 2016

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    Bearings (structural)
    Alkynes

    ASJC Scopus subject areas

    • Chemistry(all)

    Cite this

    Reaction of a stable digermyne with acetylenes : Synthesis of a 1,2-digermabenzene and a 1,4-digermabarrelene#. / Sugahara, Tomohiro; Guo, Jing Dong; Sasamori, Takahiro; Karatsu, Yusaku; Furukawa, Yukio; Ferao, Arturo Espinosa; Nagase, Shigeru; Tokitoh, Norihiro.

    In: Bulletin of the Chemical Society of Japan, Vol. 89, No. 11, 2016, p. 1375-1384.

    Research output: Contribution to journalArticle

    Sugahara, Tomohiro ; Guo, Jing Dong ; Sasamori, Takahiro ; Karatsu, Yusaku ; Furukawa, Yukio ; Ferao, Arturo Espinosa ; Nagase, Shigeru ; Tokitoh, Norihiro. / Reaction of a stable digermyne with acetylenes : Synthesis of a 1,2-digermabenzene and a 1,4-digermabarrelene#. In: Bulletin of the Chemical Society of Japan. 2016 ; Vol. 89, No. 11. pp. 1375-1384.
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    abstract = "Reactions between acetylenes and a stable digermyne bearing 4-t-Bu-2,6-[CH(SiMe3)2]2-C6H2 (Tbb) groups afforded the corresponding stable 1,2-digermabenzenes together with the respective 1,4-digermabarrelenes. The properties of the obtained products and the reaction mechanism are discussed on the basis of experimental and theoretical results. Especially, the aromaticity of the newly obtained 1,2-digermabenzene has been discussed on the detailed calculations, revealing its aromatic character to some degree.",
    author = "Tomohiro Sugahara and Guo, {Jing Dong} and Takahiro Sasamori and Yusaku Karatsu and Yukio Furukawa and Ferao, {Arturo Espinosa} and Shigeru Nagase and Norihiro Tokitoh",
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    AU - Sasamori, Takahiro

    AU - Karatsu, Yusaku

    AU - Furukawa, Yukio

    AU - Ferao, Arturo Espinosa

    AU - Nagase, Shigeru

    AU - Tokitoh, Norihiro

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