Reaction volume for the reaction of the hexaaquairon(III) ion with 4-isopropyltropolone in acidic aqueous solution

Masahiro Takagi, Koji Ishihara

Research output: Contribution to journalArticle

4 Citations (Scopus)

Abstract

The reaction volumes for the protonation of 4-isopropyltropolone (Hipt)(ΔVH°: Hipt+H+ ⇌ H2ipt+) ) and for the reaction of the Fe(III) ion with Hipt(ΔVFeL°: Fe3+ + Hipt ⇌ Fe(ipt)2+ + H+) have been determined spectrophotometrically in acidic aqueous media under pressure up to 250 MPa. The obtained values are: ΔVH° (cm3 mol-1) =+2.8±0.1, ΔVFeL° (cm3 mol-1)=7.8±0.1. The activation volume for the dissociation of Fe(ipt)2+ was calculated to be -16.5±0.9 cm3 mol-1 by using ΔVFeL° and the reported activation volume for the formation of Fe(ipt)2+. The negative volume of activation for the dissociation reaction confirms associative activation for the reaction of the Fe3+ ion.

Original languageEnglish
Pages (from-to)157-160
Number of pages4
JournalInorganica Chimica Acta
Volume232
Issue number1-2
DOIs
Publication statusPublished - 1995 Apr

Keywords

  • Activation volume
  • Iron complexes
  • Reaction volume
  • Tropolone complexes

ASJC Scopus subject areas

  • Physical and Theoretical Chemistry
  • Inorganic Chemistry
  • Materials Chemistry

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